Volume 57, Issue 9 pp. m384-m386

Bis[bis(2-pyridyl)­amine-N,N′](nitrato-O,O′)­cobalt(II) nitrate

Oscar Castillo

Oscar Castillo

Departamento de Química Inorgánica, Facultad de Ciencias, Universidad del País Vasco, Apdo. 644, E-48080 Bilbao, Spain

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Antonio Luque

Antonio Luque

Departamento de Química Inorgánica, Facultad de Ciencias, Universidad del País Vasco, Apdo. 644, E-48080 Bilbao, Spain

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Noelia De la Pinta

Noelia De la Pinta

Departamento de Química Inorgánica, Facultad de Ciencias, Universidad del País Vasco, Apdo. 644, E-48080 Bilbao, Spain

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Pascual Román

Pascual Román

Departamento de Química Inorgánica, Facultad de Ciencias, Universidad del País Vasco, Apdo. 644, E-48080 Bilbao, Spain

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First published: 03 August 2004
Antonio Luque, e-mail: [email protected]

Abstract

The crystal structure of the title compound, [Co(NO3)(C10H9N3)2]NO3, consists of mononuclear cations and uncoordinated nitrate anions held together by means of an extensive three-dimensional network of N—H⋯O and C—H⋯O hydrogen bonds. The CoII centre has a distorted octahedral geometry, coordinated with two O atoms of a bidentate nitrate ligand and with four pyridine N atoms of two bis(2-pyridyl)­amine ligands in a transtrans mode.

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