Volume 57, Issue 8 pp. m373-m375

catena-Poly­[[[(1,10-phenanthroline)­manganese(II)]-μ-(1-hydroxy­benzene-3,5-di­carboxyl­ato)] hydrate]

J. M. S. Skakle

J. M. S. Skakle

Department of Chemistry, University of Aberdeen, Meston Walk, Aberdeen AB24 3UE, Scotland

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M. R. St J. Foreman

M. R. St J. Foreman

Department of Chemistry, University of Aberdeen, Meston Walk, Aberdeen AB24 3UE, Scotland

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M. J. Plater

M. J. Plater

Department of Chemistry, University of Aberdeen, Meston Walk, Aberdeen AB24 3UE, Scotland

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First published: 03 August 2004
J. M. S. Skakle, e-mail: [email protected]

Abstract

The title compound, {[Mn(C8H4O5)(C12H8N2)]·H2O}n, forms a polymeric chain via Mn2+–C8H4O52− (Mn–HIA) dimers which zigzag parallel to [101]. The 1,10-phenanthroline mol­ecules are coordinated to the metal via the N atoms and are arranged approximately perpendicular to the Mn–HIA layers. The phenanthroline ligands are stacked parallel to one another at intervals of 3.54 Å, which is characteristic of π–π interaction.

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