Abstract
In the title compound, C3H8NO2+·C2HO4−, the alanine molecule exists in the protonated cationic form and the oxalic acid molecule in the mono-ionized state. The alanine molecules dimerize across inversion centres through head-to-tail N—H⋯O hydrogen bonds. The semi-oxalate ions aggregate into hydrogen-bonded strings along the shortest cell axis. The crystal structure is also characterized by the presence of a C—H⋯O hydrogen bond and a short C⋯O contact between amino acids.