Layered structure of catena-poly[[bis[1-(2-azidoethyl)tetrazole-N4]copper(II)]-di-μ-chloro]
Abstract
In the title compound, [CuCl2(C3H5N7)2], the coordination polyhedron of the Cu atom is an elongated square bipyramid with site symmetry. The equatorial positions are occupied by the two Cl atoms with Cu—Cl distances of 2.288 (1) Å and two azidoethyltetrazole ligands with Cu—N distances of 1.999 (2) Å. Two Cl atoms in axial positions are 2.956 (1) Å distant from the Cu atom. The Cl atoms play the role of non-symmetrical bridges responsible for formation of layers parallel to the bc plane.