Volume 57, Issue 8 pp. m335-m337

Layered structure of catena-poly­[[bis­[1-(2-azido­ethyl)­tetrazole-N4]copper(II)]-di-μ-chloro]

Dmitry O. Ivashkevich

Dmitry O. Ivashkevich

Institute of Physico-Chemical Problems, Belarusian State University, Leningradskaya Str., 14, Minsk 220050, Belarus

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Alexander S. Lyakhov

Alexander S. Lyakhov

Institute of Physico-Chemical Problems, Belarusian State University, Leningradskaya Str., 14, Minsk 220050, Belarus

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Pavel N. Gaponik

Pavel N. Gaponik

Institute of Physico-Chemical Problems, Belarusian State University, Leningradskaya Str., 14, Minsk 220050, Belarus

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Andrey N. Bogatikov

Andrey N. Bogatikov

Institute of Physico-Chemical Problems, Belarusian State University, Leningradskaya Str., 14, Minsk 220050, Belarus

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Alla A. Govorova

Alla A. Govorova

Institute of Physico-Chemical Problems, Belarusian State University, Leningradskaya Str., 14, Minsk 220050, Belarus

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First published: 03 August 2004
Citations: 5
Alexander S. Lyakhov, e-mail: [email protected]

Abstract

In the title compound, [CuCl2(C3H5N7)2], the coordination polyhedron of the Cu atom is an elongated square bipyramid with site symmetry. The equatorial positions are occupied by the two Cl atoms with Cu—Cl distances of 2.288 (1) Å and two azido­ethyl­tetrazole ligands with Cu—N distances of 1.999 (2) Å. Two Cl atoms in axial positions are 2.956 (1) Å distant from the Cu atom. The Cl atoms play the role of non-symmetrical bridges responsible for formation of layers parallel to the bc plane.

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