Bis­[S-methyl 3-(2-bromo­benzyl­idene)­di­thio­cab­aza­to-N³,S]­platinum(II)

The Schiff base ligand in the title complex, [Pt(C₉H₈BrN₂S₂)₂], is deprotonated from its tautomeric thiol form and coordinated to Pt^IIvia the mercapto S and β–N atoms. The configuration about Pt^II is a perfect square-planar, with two equivalent Pt—N [2.023 (3) Å] and Pt—S [2.293 (1) Å] bonds. The phenyl ring is twisted against the coordination moiety Pt1/N1/N1′/S2′/S2 by 31.8 (2)°, due to the steric hindrance induced by ortho-substituted bulky Br atom.