Volume 56, Issue 1 pp. 74-75

(−)-(1R,2S,2′R,5R)-2-(1-Hydroxyprop-2-yl)-5-methylcyclohexanol

Ferdinand Körner

Ferdinand Körner

Fachbereich Chemie, Universität Dortmund, Otto-Hahn-Straße 6, 44221 Dortmund, Germany

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Markus Schürmann

Markus Schürmann

Fachbereich Chemie, Universität Dortmund, Otto-Hahn-Straße 6, 44221 Dortmund, Germany

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Hans Preut

Hans Preut

Fachbereich Chemie, Universität Dortmund, Otto-Hahn-Straße 6, 44221 Dortmund, Germany

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Wolfgang Kreiser

Wolfgang Kreiser

Fachbereich Chemie, Universität Dortmund, Otto-Hahn-Straße 6, 44221 Dortmund, Germany

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First published: 01 July 2004
Citations: 1
Hans Preut, e-mail: [email protected]

Abstract

Stereoselective hydroboration of (−)-isopulegol and subsequent fractional crystallization furnishes the title compound, C10H20O2. The relative configuration of the stereogenic centres has been assigned by means of X-ray diffraction analysis since the monoterpenediol is employed as a versatile chiral building block in stereospecific natural product synthesis.

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