Volume 56, Issue 1 pp. 67-68

(−)-Sparteine copper(II) diacetate

First published: 01 July 2004
Citations: 1
Sung-Nak Choi, e-mail: [email protected]

Abstract

The chiral nitrogen-chelating alkaloid (−)-sparteine acts as a bidentate ligand, reacting with copper(II) acetate in ethanol to form the title complex, [Cu(CH3COO)2(C15H26N2)], with the two acetate groups occupying the remaining coordination sites in a monodentate fashion to produce a distorted four-coordinate tetrahedral structure. The dihedral angle between the N—Cu—N and O—Cu—O planes is 45.8 (3)°.

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