Volume 60, Issue 8 pp. m405-m406

Chloro­(phenyl)(1H-pyrazole-κN2)(tri­phenyl­phosphine-κP)­palladium(II)

First published: 05 August 2004
Brian W. Skelton, e-mail: [email protected]

Abstract

In the title compound, [Pd(C6H5)Cl(C3H4N2){P(C6H5)3}], the phenyl and Cl ligands lie mutually trans. The compound is the first structurally characterized complex with four mono­dentate Cl, P, N and (non-carbenoid) C ligands in a square-planar four-coordinate palladium(II) environment. The pyrazole ligand is coplanar with the latter array. The pyrazole NH group forms a bifurcated hydrogen bond to Cl, with an intra- and intermolecular component.

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