Volume 60, Issue 8 pp. m371-m372

catena-Poly­[[[aqua­copper(I)]-μ-4,4′-bipyridyl-κ2N:N′] hemi­(isophthalate) monohydrate]

Yi-Hang Wen

Yi-Hang Wen

The State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, People's Republic of China

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Ye-Yan Qin

Ye-Yan Qin

The State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, People's Republic of China

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Jian Zhang

Jian Zhang

The State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, People's Republic of China

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Zhao-Ji Li

Zhao-Ji Li

The State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, People's Republic of China

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Jian-Kai Cheng

Jian-Kai Cheng

The State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, People's Republic of China

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Yao Kang

Yao Kang

The State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, People's Republic of China

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Yuan-Gen Yao

Yuan-Gen Yao

The State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, People's Republic of China

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First published: 05 August 2004
Yuan-Gen Yao, e-mail: [email protected]

Abstract

The title compound, {[Cu(C10H8N2)(H2O)](C8H4O4)0.5·H2O}n, has been synthesized hydro­thermally and characterized by single-crystal X-ray diffraction. The compound consists of nearly linear one-dimensional chains of [Cu(4,4′-bipy)(H2O)]nn+ cations (4,4′-bipy is 4,4′-bipyridyl), surrounded by isophthalate anions and free water mol­ecules. Hydro­gen-bonding interactions involving cationic chains, isophthalate anions and free water mol­ecules lead to the formation of a three-dimensional network structure.

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