{Bis[2-(2-oxido-1-naphthylmethylideneamino)phenyl] disulfide}chloroiron(III)
Abstract
The crystal structure of the title compound, {bis[2-(2-oxido-2-naphthylideneamino)phenyl] disulfide-κ5O,N,S,N′,O′}chloroiron(III), [FeCl(C34H22N2O2S2)], has been determined. The structure consists of monomeric iron(III) complexes with distorted octahedral coordination. The disulfide functions as a pentadentate ligand and the FeIII atom is coordinated through two N, two O and one S atom, and one chloride ion. The distance between the second S atom and the FeIII atom is a non-bonding 3.8473 (14) Å.