Volume 57, Issue 4 pp. 439-440

3,3′-Seleno­bis­(propionic acid)

Khaled I. Doudin

Khaled I. Doudin

Department of Chemistry, University of Bergen, Allégaten 41, 5007 Bergen, Norway

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Jon Songstad

Jon Songstad

Department of Chemistry, University of Bergen, Allégaten 41, 5007 Bergen, Norway

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Karl W. Törnroos

Karl W. Törnroos

Department of Chemistry, University of Bergen, Allégaten 41, 5007 Bergen, Norway

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First published: 23 June 2004
Karl W. Törnroos, e-mail: [email protected]

Abstract

In contrast to Se[CH2C(O)OH]2versus S[CH2C(O)OH]2, the title compound, Se[CH2CH2C(O)OH]2 or C6H10O4Se, is structurally quite similar to its sulfur analogue. The mol­ecule has twofold symmetry. The C—Se—C bond angle is 96.48 (8)° and the Se—C bond lengths are 1.9610 (14) Å. The shortest Se⃛O intermolecular distance is 3.5410 (11) Å. The O⃛O distances in the carboxyl­ic acid dimers are 2.684 (2) Å. The temperature dependence of the IR spectrum suggests tautomerism in the solid state.

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