Volume 57, Issue 4 pp. 356-358

[2-(Imidazol-4-yl)ethylamine]{[2-(imidazol-4-yl)ethyl][(1-methylimidazol-2-yl)methyl]amine}copper(II) diperchlorate

Marciela Scarpellini

Marciela Scarpellini

Departamento de Química – UFSC, 88040-900 – Florianópolis SC, Brazil

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Ademir Neves

Ademir Neves

Departamento de Química – UFSC, 88040-900 – Florianópolis SC, Brazil

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Adailton J. Bortoluzzi

Adailton J. Bortoluzzi

Departamento de Química – UFSC, 88040-900 – Florianópolis SC, Brazil

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Antônio C. Joussef

Antônio C. Joussef

Departamento de Química – UFSC, 88040-900 – Florianópolis SC, Brazil

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First published: 23 June 2004
Citations: 1
Marciela Scarpellini, e-mail: [email protected]

Abstract

In the title mononuclear complex, [Cu(C5H9N3)(C10H15N5)](ClO4)2, the CuII centre is surrounded by two N-donor ligands, which impose a square-pyramidal environment on the metal. The new tridentate ligand [2-(imidazol-4-yl)­ethyl]­[(1-methyl­imidazol-2-yl)­methyl]­amine (HISMIMA) lies in the basal plane, while the hist­amine ligand occupies the apical and one of the basal positions around the CuII ion.

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