20-Dicyanomethylene-5,8,11,14-tetraoxa-2,17-dithiabicyclo[16.4.1]tricosa-1(23),18,21-triene and its mercury(II) dichloride complex
Abstract
The structures of the title compound, C20H24N2O4S2, and its mercury(II) dichloride complex, dichloro{20-dicyanomethylene-5,8,11,14-tetraoxa-2,17-dithiabicyclo[16.4.1]tricosa-1(23),18,21-triene-κ4O,κS17}mercury(II), [HgCl2(C20H24N2O4S2)], have been determined by X-ray crystallographic analyses. The mercury(II) dichloride complex has two independent molecules of [HgCl2(C20H24N2O4S2)] in the lattice. The mercury(II) ion has pentagonal bipyramidal coordination which involves one S atom, four O atoms and two Cl− ions.