Volume 56, Issue 6 pp. 644-646

20-Di­cyano­methyl­ene-5,8,11,14-tetraoxa-2,17-di­thia­bi­cyclo­[16.4.1]­tricosa-1(23),18,21-triene and its mercury(II) dichloride complex

Kanji Kubo

Kanji Kubo

Institute of Advanced Material Study, 86, Kyushu University, Kasuga-koen, Kasuga, Fukuoka 816-8580, Japan

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Nobuo Kato

Nobuo Kato

Institute of Advanced Material Study, 86, Kyushu University, Kasuga-koen, Kasuga, Fukuoka 816-8580, Japan

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Akira Mori

Akira Mori

Institute of Advanced Material Study, 86, Kyushu University, Kasuga-koen, Kasuga, Fukuoka 816-8580, Japan

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Hitoshi Takeshita

Hitoshi Takeshita

Institute of Advanced Material Study, 86, Kyushu University, Kasuga-koen, Kasuga, Fukuoka 816-8580, Japan

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First published: 30 June 2004
Citations: 1
Kanji Kubo, e-mail: [email protected]

Abstract

The structures of the title compound, C20H24N2O4S2, and its mercury(II) dichloride complex, dichloro{20-di­cyano­methyl­ene-5,8,11,14-tetraoxa-2,17-di­thia­bi­cyclo­[16.4.1]­tricosa-1(23),18,­21-tri­ene-κ4OS17}mercury(II), [HgCl2(C20­H24­N2­O4­S2)], have been determined by X-ray crystallographic analyses. The mercury(II) dichloride complex has two independent mol­ecules of [HgCl2(C20H24N2O4S2)] in the lattice. The mercury(II) ion has pentagonal bipyramidal coordination which involves one S atom, four O atoms and two Cl ions.

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