Es werden die Röntgenstrukturanalysen von Dimethylaminoalan (I), Bis(dimethylamino)alan (II) und Tris(dimethylamino)alan (III) mitgeteilt und deren Molekülspektren diskutiert. I ist trimer und liegt als Sechsring in der Sesselform vor; II und III sind dimer und bilden planare Vierringe aus.

Abstract

Dimethylaminoalanes, H_{3 − n}Al[N(CH₃)₂]_n, n = 1, 2, 3; Crystal Structures and Molecular Spectra

The X-ray crystal structure analyses of dimethylaminoalane (I), bis(dimethylamino)alane, and tris(dimethylamino)alane are reported and the molecular spectra of these compounds are discussed. I is trimeric and exists as sixmembered ring of a chair-conformation. II and III are dimeric and build up planar four-membered rings.

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Volume504, Issue9

September 1983

Pages 67-76

Dimethylaminoalane, H_{3 − n} Al[N(CH₃)₂]_n, n = 1, 2, 3 Kristallstrukturen und Molekülspektren

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Dimethylaminoalane, H3 − n Al[N(CH3)2]n, n = 1, 2, 3 Kristallstrukturen und Molekülspektren

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Dimethylaminoalane, H_{3 − n} Al[N(CH₃)₂]_n, n = 1, 2, 3 Kristallstrukturen und Molekülspektren