The Reaction of Titanium Tetrachloride with acetic acid and 1–4 dioxane
Abstract
enA procedure for the preparation of anhydrous titanium acetate is given. The yellow colored product has the formula Ti(C2H3O2)4 · 2 (CH3COOH. The reaction between TiCl4 and 1–4 dioxane resulted in the formation of titanium (IV) tetrachloro monodioxanate. This yellow compound was found to decompose at about 190°C. Partial hydrolysis of this compound resulted in the formation of titanium (IV) dichloro dihydroxy monodioxanate, a white compound. The latter complex was soluble in acetone, ethyl ether, water, and decomposed when heated above 300°C.
Abstract
deWasserfreies gelbes Titan(IV)-acetat der Formel Ti(OOCCH3) · 2 CH3COOH wurde aus TiCl4 und Eisessig in Äther erhalten. Aus TiCl4 und 1.4-Dioxan bildet sich ein gelbes 1:1-Addukt (Zers. ∼190°C), das bei partieller Hydrolyse das farblose TiCl2(OH)2 · diox ergibt. Letzteres ist löslich in Aceton, Äthyläther und Wasser und zersetzt sich oberhalb 300°C.
