Highly Crystalline and Robust Donor-Acceptor Type Covalent Organic Frameworks for Long-life Sodium-Ion Battery Cathodes
Kun Kang
School of Materials Science and Engineering, Shaanxi Normal University, Xi'an, 710119 P. R. China
Search for more papers by this authorYing Liu
College of Chemistry and Environmental Engineering, Anyang Institute of Technology, Anyang, 455000 P. R. China
Search for more papers by this authorJiaqi Duan
School of Materials Science and Engineering, Shaanxi Normal University, Xi'an, 710119 P. R. China
Search for more papers by this authorXue Tang
School of Materials Science and Engineering, Shaanxi Normal University, Xi'an, 710119 P. R. China
Search for more papers by this authorYan Wang
School of Materials Science and Engineering, Tongji University, Shanghai, 200092 P. R. China
Search for more papers by this authorShiqi Zhang
School of Mechanical Engineering, Nantong University, Nantong, 226019 P. R. China
Search for more papers by this authorHeng Wang
School of Mechanical Engineering, Nantong University, Nantong, 226019 P. R. China
Search for more papers by this authorJincan Cui
School of Mechanical Engineering, Nantong University, Nantong, 226019 P. R. China
Search for more papers by this authorXiaolei Yuan
School of Mechanical Engineering, Nantong University, Nantong, 226019 P. R. China
Search for more papers by this authorXu Deng
College of Chemistry and Environmental Engineering, Anyang Institute of Technology, Anyang, 455000 P. R. China
College of Chemistry and Chemical Engineering, Henan Polytechnic University, Jiaozuo, 454003 P. R. China
Search for more papers by this authorCorresponding Author
Ning Fu
College of Chemistry and Environmental Engineering, Anyang Institute of Technology, Anyang, 455000 P. R. China
College of Chemistry and Chemical Engineering, Henan Polytechnic University, Jiaozuo, 454003 P. R. China
E-mail: [email protected]; [email protected]; [email protected]
Search for more papers by this authorCorresponding Author
Ben Yang
School of Materials Science and Engineering, Shaanxi Normal University, Xi'an, 710119 P. R. China
E-mail: [email protected]; [email protected]; [email protected]
Search for more papers by this authorCorresponding Author
Jian-Yong Hu
School of Materials Science and Engineering, Shaanxi Normal University, Xi'an, 710119 P. R. China
E-mail: [email protected]; [email protected]; [email protected]
Search for more papers by this authorKun Kang
School of Materials Science and Engineering, Shaanxi Normal University, Xi'an, 710119 P. R. China
Search for more papers by this authorYing Liu
College of Chemistry and Environmental Engineering, Anyang Institute of Technology, Anyang, 455000 P. R. China
Search for more papers by this authorJiaqi Duan
School of Materials Science and Engineering, Shaanxi Normal University, Xi'an, 710119 P. R. China
Search for more papers by this authorXue Tang
School of Materials Science and Engineering, Shaanxi Normal University, Xi'an, 710119 P. R. China
Search for more papers by this authorYan Wang
School of Materials Science and Engineering, Tongji University, Shanghai, 200092 P. R. China
Search for more papers by this authorShiqi Zhang
School of Mechanical Engineering, Nantong University, Nantong, 226019 P. R. China
Search for more papers by this authorHeng Wang
School of Mechanical Engineering, Nantong University, Nantong, 226019 P. R. China
Search for more papers by this authorJincan Cui
School of Mechanical Engineering, Nantong University, Nantong, 226019 P. R. China
Search for more papers by this authorXiaolei Yuan
School of Mechanical Engineering, Nantong University, Nantong, 226019 P. R. China
Search for more papers by this authorXu Deng
College of Chemistry and Environmental Engineering, Anyang Institute of Technology, Anyang, 455000 P. R. China
College of Chemistry and Chemical Engineering, Henan Polytechnic University, Jiaozuo, 454003 P. R. China
Search for more papers by this authorCorresponding Author
Ning Fu
College of Chemistry and Environmental Engineering, Anyang Institute of Technology, Anyang, 455000 P. R. China
College of Chemistry and Chemical Engineering, Henan Polytechnic University, Jiaozuo, 454003 P. R. China
E-mail: [email protected]; [email protected]; [email protected]
Search for more papers by this authorCorresponding Author
Ben Yang
School of Materials Science and Engineering, Shaanxi Normal University, Xi'an, 710119 P. R. China
E-mail: [email protected]; [email protected]; [email protected]
Search for more papers by this authorCorresponding Author
Jian-Yong Hu
School of Materials Science and Engineering, Shaanxi Normal University, Xi'an, 710119 P. R. China
E-mail: [email protected]; [email protected]; [email protected]
Search for more papers by this authorAbstract
Covalent organic frameworks (COFs) hold great potential in sodium-ion battery cathodes. However, most reported COF-based electrodes show unsatisfying capacity and rate performance due to their limited redox site density, low crystallinity, and poor conductivity. Herein, a highly crystalline and robust donor-acceptor type COF with abundant redox active sites is developed by the polymerization of donor unit benzo[1,2-b:3,4-b″:5,6-b″']trithiophene-2,5,8-tricarbaldehyde) (BTT) and acceptor unit s-indacene-1,3,5,7(2H,6H)-tetrone (ICTO) (denoted as BTT-ICTO) for cathodic Na+ storage. The BTT-ICTO-graphene composites (BTT-ICTO@G) synthesized by in situ growth have a loose sheet structure with rough surfaces, contributing to the improved conductivity and active site utilization of BTT-ICTO. Benefiting from the robustness of BTT-ICTO linked by ethylene bonds, the BTT-ICTO@G cathodes exhibit a high capacity of 325 mAh g−1 at 0.1 A g−1 with a high active site utilization of 80%, excellent rate performance of 190 mAh g−1 at 5.0 A g−1, and exceptional cycle performances of 196 mAh g−1 over 10 000 cycles at 2.0 A g−1 with only 0.0015% decay per cycle. These properties make the BTT-ICTO@G cathodes among the best-reported COF-based sodium-ion battery cathodes. In addition, in situ Raman, ex situ Fourier transform infrared, and theoretical calculations disclose the reaction pathway of Na+ storage.
Conflict of Interest
The authors declare no conflict of interest.
Open Research
Data Availability Statement
The data that support the findings of this study are available from the corresponding author upon reasonable request.
Supporting Information
| Filename | Description |
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| smll202412698-sup-0001-SuppMat.docx9 MB | Supporting Information |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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