Decoding Framework Dynamics in a Spin Crossover Flexible Metal–Organic Framework
Ana Martinez-Martinez
IMDEA Nanociencia, C/ Faraday 9, Madrid, 28049 Spain
Search for more papers by this authorJorge Albalad
Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC and The Barcelona Institute of Science and Technology, Campus UAB, Bellaterra, Barcelona, 08193 Spain
Departament de Química, Facultat de Ciències, Universitat Autònoma de Barcelona, Bellaterra, Barcelona, 08193 Spain
Search for more papers by this authorEsther Resines-Urien
IMDEA Nanociencia, C/ Faraday 9, Madrid, 28049 Spain
Search for more papers by this authorCorresponding Author
E. Carolina Sañudo
Departament de Química Inorgànica i Orgànica, Secció de Química Inorgànica, Universidad de Barcelona, C/Martí i Franqués 1–11, Barcelona, 08028 Spain
IN2UB Institute de Nanociencia i Nanotecnologia, Universitat de Barcelona C/Marti i Franques 1-11, Barcelona, 08028 Spain
E-mail: [email protected]; [email protected]; [email protected]
Search for more papers by this authorA. Lorenzo Mariano
CNRS, SIMAP, Univ. Grenoble Alpes, Grenoble, 38000 France
Search for more papers by this authorOscar Fabelo
Institut Laue-Langevin, 6 rue Jules Horowitz, BP 156, Grenoble, Cedex 938042 France
Search for more papers by this authorJose Alberto Rodríguez-Velamazán
Institut Laue-Langevin, 6 rue Jules Horowitz, BP 156, Grenoble, Cedex 938042 France
Search for more papers by this authorCorresponding Author
Roberta Poloni
CNRS, SIMAP, Univ. Grenoble Alpes, Grenoble, 38000 France
E-mail: [email protected]; [email protected]; [email protected]
Search for more papers by this authorDaniel Maspoch
Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC and The Barcelona Institute of Science and Technology, Campus UAB, Bellaterra, Barcelona, 08193 Spain
Departament de Química, Facultat de Ciències, Universitat Autònoma de Barcelona, Bellaterra, Barcelona, 08193 Spain
ICREA, Pg. Lluís Companys 23, Barcelona, 08010 Spain
Search for more papers by this authorCorresponding Author
José Sánchez Costa
IMDEA Nanociencia, C/ Faraday 9, Madrid, 28049 Spain
E-mail: [email protected]; [email protected]; [email protected]
Search for more papers by this authorAna Martinez-Martinez
IMDEA Nanociencia, C/ Faraday 9, Madrid, 28049 Spain
Search for more papers by this authorJorge Albalad
Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC and The Barcelona Institute of Science and Technology, Campus UAB, Bellaterra, Barcelona, 08193 Spain
Departament de Química, Facultat de Ciències, Universitat Autònoma de Barcelona, Bellaterra, Barcelona, 08193 Spain
Search for more papers by this authorEsther Resines-Urien
IMDEA Nanociencia, C/ Faraday 9, Madrid, 28049 Spain
Search for more papers by this authorCorresponding Author
E. Carolina Sañudo
Departament de Química Inorgànica i Orgànica, Secció de Química Inorgànica, Universidad de Barcelona, C/Martí i Franqués 1–11, Barcelona, 08028 Spain
IN2UB Institute de Nanociencia i Nanotecnologia, Universitat de Barcelona C/Marti i Franques 1-11, Barcelona, 08028 Spain
E-mail: [email protected]; [email protected]; [email protected]
Search for more papers by this authorA. Lorenzo Mariano
CNRS, SIMAP, Univ. Grenoble Alpes, Grenoble, 38000 France
Search for more papers by this authorOscar Fabelo
Institut Laue-Langevin, 6 rue Jules Horowitz, BP 156, Grenoble, Cedex 938042 France
Search for more papers by this authorJose Alberto Rodríguez-Velamazán
Institut Laue-Langevin, 6 rue Jules Horowitz, BP 156, Grenoble, Cedex 938042 France
Search for more papers by this authorCorresponding Author
Roberta Poloni
CNRS, SIMAP, Univ. Grenoble Alpes, Grenoble, 38000 France
E-mail: [email protected]; [email protected]; [email protected]
Search for more papers by this authorDaniel Maspoch
Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC and The Barcelona Institute of Science and Technology, Campus UAB, Bellaterra, Barcelona, 08193 Spain
Departament de Química, Facultat de Ciències, Universitat Autònoma de Barcelona, Bellaterra, Barcelona, 08193 Spain
ICREA, Pg. Lluís Companys 23, Barcelona, 08010 Spain
Search for more papers by this authorCorresponding Author
José Sánchez Costa
IMDEA Nanociencia, C/ Faraday 9, Madrid, 28049 Spain
E-mail: [email protected]; [email protected]; [email protected]
Search for more papers by this authorAbstract
Functional spin crossover (SCO) metal–organic frameworks (MOFs) hold promise for miniaturized spin-based devices due to their tuneable molecule-based properties near room temperature. SCO describes the phenomenon where transition metal ions switch between high spin (HS) and low spin (LS) states upon external stimuli. However, even simple guest molecules like water can significantly alter the properties of these materials. Understanding the interplay between SCO and these molecules is therefore crucial. This work investigates this interplay in a fascinating 3D Fe(II) SCO-MOF, recently reported to exhibit reversible conductivity even in bulk. A combined experimental and computational approach is employed to explore how guest molecule uptake/release influences SCO dynamics including a transition from partial HS/LS to a fully LS state at high temperatures, (named reverse SCO) and ligand disorder-order behavior. The findings reveal a solid-state mechanism that differs from those previously described.
Conflict of Interest
The authors declare no conflict of interest.
Open Research
Data Availability Statement
The data that support the findings of this study are available in the supplementary material of this article.
Supporting Information
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| smll202411201-sup-0001-SuppMat.docx1.1 MB | Supporting Information |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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