Platinum/(Carbon-Nanotube) Electrocatalyst Boosts Hydrogen Evolution Reaction in Acidic, Neutral and Alkaline Solutions
Yi Liu
School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240 P. R. China
Search for more papers by this authorPeng Liu
School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240 P. R. China
Search for more papers by this authorYingying Cai
State Key Laboratory of Green Chemical Engineering and Industrial Catalysis, School of Chemical Engineering, East China University of Science and Technology, Shanghai, 200237 P. R. China
Search for more papers by this authorMinghui Zhu
State Key Laboratory of Green Chemical Engineering and Industrial Catalysis, School of Chemical Engineering, East China University of Science and Technology, Shanghai, 200237 P. R. China
Search for more papers by this authorNing Dou
Department of Thyroid Breast and Vascular Surgery, Shanghai Fourth People's Hospital Affiliated To Tongji University School of Medicine, Shanghai, 200081 P. R. China
Search for more papers by this authorCorresponding Author
Lei Zhang
Department of Vascular Surgery, Changhai Hospital, Naval Medical University, Shanghai, 200433 P. R. China
E-mail: [email protected]; [email protected]
Search for more papers by this authorYu-Long Men
School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240 P. R. China
Search for more papers by this authorCorresponding Author
Yun-Xiang Pan
School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240 P. R. China
E-mail: [email protected]; [email protected]
Search for more papers by this authorYi Liu
School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240 P. R. China
Search for more papers by this authorPeng Liu
School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240 P. R. China
Search for more papers by this authorYingying Cai
State Key Laboratory of Green Chemical Engineering and Industrial Catalysis, School of Chemical Engineering, East China University of Science and Technology, Shanghai, 200237 P. R. China
Search for more papers by this authorMinghui Zhu
State Key Laboratory of Green Chemical Engineering and Industrial Catalysis, School of Chemical Engineering, East China University of Science and Technology, Shanghai, 200237 P. R. China
Search for more papers by this authorNing Dou
Department of Thyroid Breast and Vascular Surgery, Shanghai Fourth People's Hospital Affiliated To Tongji University School of Medicine, Shanghai, 200081 P. R. China
Search for more papers by this authorCorresponding Author
Lei Zhang
Department of Vascular Surgery, Changhai Hospital, Naval Medical University, Shanghai, 200433 P. R. China
E-mail: [email protected]; [email protected]
Search for more papers by this authorYu-Long Men
School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240 P. R. China
Search for more papers by this authorCorresponding Author
Yun-Xiang Pan
School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai, 200240 P. R. China
E-mail: [email protected]; [email protected]
Search for more papers by this authorAbstract
Widely used catalysts for electrocatalytic hydrogen (H2) evolution reaction (HER) have high platinum (Pt) contents and show low efficiencies in neutral and alkaline solutions. Herein, a carbon nanotube (CNT) supported Pt catalyst (Pt/CNT45) with 1 wt.% Pt is fabricated. For HER, the mass activity of Pt/CNT45 in acidic (18.76 A mgPt−1), neutral (3.92 A mgPt−1), and alkaline (3.88 A mgPt−1) solutions is respectively much higher than those on commercial Pt/C catalyst with 20 wt.% Pt (acidic: 0.31 A mgPt−1, neutral: 0.03 A mgPt−1, alkaline: 0.07 A mgPt−1). Thus, Pt/CNT45 enhances HER not only in acidic solutions but also in neutral and alkaline solutions. Ptδ+ at Pt-CNT interface on Pt/CNT45 promotes water (H2O) dissociation and hydroxyl (OH) desorption from Pt/CNT45, thus enhancing HER. This work opens a new way for enhancing HER in a wider pH range by catalyst with low Pt content, and helpful for commercialization.
Conflict of Interest
The authors declare no conflict of interest.
Open Research
Data Availability Statement
The data that support the findings of this study are available from the corresponding author upon reasonable request.
Supporting Information
| Filename | Description |
|---|---|
| smll202411181-sup-0001-SuppMat.docx6.5 MB | Supporting Information |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
References
- 1J. A. Turner, ScienceScience. 2004, 305, 972.
- 2D. Yan, C. Mebrahtu, S. Wang, R. Palkovits, Angew. Chem., Int. Ed. 2023, 62, 202214333.
- 3S. Park, L. Liu, Ç. Demirkır, O. van der Heijden, D. Lohse, D. Krug, M. T. M. Koper, Nat. Chem. 2023, 15, 1532.
- 4Q.-Q. Yan, D.-X. Wu, S.-Q. Chu, Z.-Q. Chen, Y. Lin, M.-X. Chen, J. Zhang, X.-J. Wu, H.-W. Liang, Nat. Commun. 2019, 10, 4977.
- 5C. Wan, Z. Zhang, J. Dong, M. Xu, H. Pu, D. Baumann, Z. Lin, S. Wang, J. Huang, A. H. Shah, X. Pan, T. Hu, A. N. Alexandrova, Y. Huang, X. Duan, Nat. Mater. 2023, 22, 1022.
- 6X. Cheng, C. Mao, J. Tian, M. Xia, L. Yang, X. Wang, Q. Wu, Z. Hu, Angew. Chem., Int. Ed. 2024, 63, 202401304.
- 7P. Kuang, Y. Wang, B. Zhu, F. Xia, C.-W. Tung, J. Wu, H. M. Chen, J. Yu, Adv. Mater. 2021, 33, 2008599.
- 8H. Zhai, P. Tan, M. Jiang, M. Zhang, R. Ren, R. Sa, J. Pan, ACS Catal. 2023, 13, 8063.
- 9K. Jiang, X.-Y. Ma, S. Back, J. Zhao, F. Jiang, X. Qin, J. Zhang, W.-B. Cai, CCS Chem. 2021, 3, 241.
- 10Y. Zhao, P. V. Kumar, X. Tan, X. Lu, X. Zhu, J. Jiang, J. Pan, S. Xi, H. Yang, Z. Ma, T. Wan, D. Chu, W. Jiang, S. C. Smith, R. Amal, Z. Han, X. Lu, Nat. Commun. 2022, 10, 2430.
10.1038/s41467-022-30155-4 Google Scholar
- 11R. Zhang, Y. Li, X. Zhou, A. Yu, Q. Huang, T. Xu, L. Zhu, P. Peng, S. Song, L. Echegoyen, F.-F. Li, Nat. Commun. 2023, 14, 2460.
- 12Y. Zhu, M. Klingenhof, C. Gao, T. Koketsu, G. Weiser, Y. Pi, S. Liu, L. Sui, J. Hou, J. Li, H. Jiang, L. Xu, W.-H. Huang, C.-W. Pao, M. Yang, Z. Hu, P. Strasser, J. Ma, Nat. Commun. 2024, 15, 1447.
- 13J. Zhao, C. Fu, K. Ye, Z. Liang, F. Jiang, S. Shen, X. Zhao, L. Ma, Z. Shadike, X. Wang, J. Zhang, K. Jiang, Nat. Commun. 2022, 13, 685.
- 14F. Wu, L. Zeng, A. Pei, Y. Feng, L. Zhu, J. Mater. Chem. A. 2024, 12, 10300.
- 15J. Li, Y. Zhou, W. Tang, J. Zheng, X. Gao, N. Wang, X. Chen, M. Wei, X. Xiao, W. Chu, Appl. Catal. B: Environ. 2021, 285, 119861.
- 16Y. Qu, B. Chen, Z. Li, X. Duan, L. Wang, Y. Lin, T. Yuan, F. Zhou, Y. Hu, Z. Yang, C. Zhao, J. Wang, C. Zhao, Y. Hu, G. Wu, Q. Zhang, Q. Xu, B. Liu, P. Gao, R. You, W. Huang, L. Zheng, L. Gu, Y. Wu, Y. Li, J. Am. Chem. Soc. 2019, 141, 4505.
- 17Q. Yang, H. Liu, P. Yuan, Y. Jia, L. Zhuang, H. Zhang, X. Yan, G. Liu, Y. Zhao, J. Liu, S. Wei, L. Song, Q. Wu, B. Ge, L. Zhang, K. Wang, X. Wang, C.-R. Chang, X. Yao, J. Am. Chem. Soc. 2022, 144, 2171.
- 18P. Liu, Y.-L. Men, X.-Y. Meng, C. Peng, Y. Zhao, Y.-X. Pan, Angew. Chem., Int. Ed. 2023, 62, 2023094.
- 19X.-Y. Meng, J.-J. Li, P. Liu, M. Duan, J. Wang, Y.-N. Zhou, Y. Xie, Z.-H. Luo, Y.-X. Pan, Angew. Chem., Int. Ed. 2023, 62, 202307490.
- 20Y.-L. Men, P. Liu, Y. Liu, X.-Y. Meng, Y.-X. Pan, Ind. Eng. Chem. Res. 2022, 61, 4300.
- 21P. Liu, L. Niu, Y.-L. Men, C. Peng, Z. Liu, X.-Y. Meng, Y.-X. Pan, Appl. Catal. B: Environ. 2023, 320, 121985.
- 22J. Yang, Z. Ju, Y. Jiang, Z. Xing, B. Xi, J. Feng, S. Xiong, Adv. Mater. 2018, 30, 1700104.
- 23J. Lu, C. Wang, H. Yu, S. Gong, G. Xia, P. Jiang, P. Xu, K. Yang, Q. Chen, Adv. Funct. Mater. 2019, 29, 1906126.
- 24C. Duong-Viet, Y. Liu, H. Ba, L. Truong-Phuoc, W. Baaziz, L. Nguyen-Dinh, J. M. Nhut, C. Pham-Huu, Appl. Catal. B: Environ. 2016, 191, 29.
- 25X. Shi, C. Dai, X. Wang, J. Hu, J. Zhang, L. Zheng, L. Mao, H. Zheng, M. Zhu, Nat. Commun. 2022, 13, 1287.
- 26F. Bernardi, M. C. M. Alves, J. Morais, J. Phys. Chem. C. 2010, 114, 21434.
- 27Z. Zhang, Z. Zhang, C. Chen, R. Wang, M. Xie, S. Wan, R. Zhang, L. Cong, H. Lu, Y. Han, W. Xing, Z. Shi, S. Feng, Nat. Commun. 2024, 15, 2556.
- 28A. Han, X. Wang, K. Tang, Z. Zhang, C. Ye, K. Kong, H. Hu, L. Zheng, P. Jiang, C. Zhao, Q. Zhang, D. Wang, Y. Li, Angew. Chem., Int. Ed. 2021, 60, 19262.
- 29Y.-X. Pan, H.-P. Cong, Y.-L. Men, S. Xin, Z.-Q. Sun, C.-J. Liu, S.-H. Yu, ACS Nano. 2015, 9, 11258.
- 30B. Zhao, X. Wang, P. Liu, Y. Zhao, Y.-L. Men, Y.-X. Pan, Ind. Eng. Chem. Res. 2022, 61, 6845.
- 31P. Liu, X. Zou, X.-Y. Meng, C. Peng, X. Li, Y. Wang, F. Zhao, Y.-X. Pan, AIChE J. 2023, 69, 18016.
- 32K. Sun, X. Wu, Z. Zhuang, L. Liu, J. Fang, L. Zeng, J. Ma, S. Liu, J. Li, R. Dai, X. Tan, K. Yu, D. Liu, W.-C. Cheong, A. Huang, Y. Liu, Y. Pan, H. Xiao, C. Chen, Nat. Commun. 2022, 13, 6260.
- 33J. Le, Q. Fan, L. Perez-Martinez, A. Cuesta, J. Cheng, Phys. Chem. Chem. Phys. 2018, 20, 11554.
- 34M. Wang, K. Sun, W. Mi, C. Feng, Z. Guan, Y. Liu, Y. Pan, ACS Catal. 2022, 12, 10771.
- 35L.-F. Shen, B.-A. Lu, Y.-Y. Li, J. Liu, Z.-C. Huang-fu, H. Peng, J.-Y. Ye, X.-M. Qu, J.-M. Zhang, G. Li, W.-B. Cai, Y.-X. Jiang, S.-G. Sun, Angew. Chem., Int. Ed. 2020, 59, 22397.
- 36Y.-H. Wang, S. Zheng, W.-M. Yang, R.-Y. Zhou, Q.-F. He, P. Radjenovic, J.-C. Dong, S. Li, J. Zheng, Z.-L. Yang, G. Attard, F. Pan, Z.-Q. Tian, J.-F. Li, NatureNature. 2021, 600, 81.
- 37X. Chen, X.-T. Wang, J.-B. Le, S.-M. Li, X. Wang, Y.-J. Zhang, P. Radjenovic, Y. Zhao, Y.-H. Wang, X.-M. Lin, J.-C. Dong, J.-F. Li, Nat. Commun. 2023, 14, 5289.
- 38X. Zheng, X. Shi, H. Ning, R. Yang, B. Lu, Q. Luo, S. Mao, L. Xi, Y. Wang, Nat. Commun. 2023, 14, 4209.
- 39J. Wu, X. Wang, W. Zheng, Y. Sun, Y. Xie, K. Ma, Z. Zhang, Q. Liao, Z. Tian, Z. Kang, Y. Zhang, J. Am. Chem. Soc. 2022, 144, 19163.
- 40W. Chen, B. Wu, Y. Wang, W. Zhou, Y. Li, T. Liu, C. Xie, L. Xu, S. Du, M. Song, D. Wang, Y. Liu, Y. Li, J. Liu, C. Chen, J. Zheng, S. Wang, Energy Environ. Sci. 2021, 14, 6428.
