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On the Temperature Behavior of Optical Gap in Arsenic Sulfide Glasses

James Forsythe

Department of Physics, Engineering and Astronomy, Austin Peay State University, 601 College St., Clarksville, TN, 37044 USA

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Mykhaylo Shpotyuk,

Mykhaylo Shpotyuk

Department of Semiconductor Electronics, Lviv Polytechnic National University, 12, Bandera str., Lviv, UA-79013 Ukraine

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Oleh Shpotyuk,

Oleh Shpotyuk

Faculty of Science and Technology, Jan Dlugosz University in Czestochowa, 13/15, al. Armii Krajowej, Czestochowa, 42200 Poland

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Roman Golovchak,

Corresponding Author

Roman Golovchak

[email protected]

orcid.org/0000-0002-2580-1029

Department of Physics, Engineering and Astronomy, Austin Peay State University, 601 College St., Clarksville, TN, 37044 USA

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James Forsythe,

James Forsythe

Department of Physics, Engineering and Astronomy, Austin Peay State University, 601 College St., Clarksville, TN, 37044 USA

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Mykhaylo Shpotyuk,

Mykhaylo Shpotyuk

Department of Semiconductor Electronics, Lviv Polytechnic National University, 12, Bandera str., Lviv, UA-79013 Ukraine

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Oleh Shpotyuk,

Oleh Shpotyuk

Faculty of Science and Technology, Jan Dlugosz University in Czestochowa, 13/15, al. Armii Krajowej, Czestochowa, 42200 Poland

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Roman Golovchak,

Corresponding Author

Roman Golovchak

[email protected]

orcid.org/0000-0002-2580-1029

Department of Physics, Engineering and Astronomy, Austin Peay State University, 601 College St., Clarksville, TN, 37044 USA

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First published: 28 October 2021

https://doi.org/10.1002/pssb.202100404

Citations: 2

The data that support the findings of this study are available from the corresponding author upon reasonable request.

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Abstract

Temperature behavior of optical transmission in the fundamental optical absorption edge region is studied for a broad range of As–S glass compositions covering the entire glass-forming interval. It is shown that temperature dependences of optical gap values for all bulk glasses can be well fitted by the one-phonon approximation based on Bose–Einstein statistics. Correlation of fitting parameters with thermodynamic data and compositional structural development published earlier is discussed.

Conflict of Interest

The authors declare no conflict of interest.

Open Research

Data Availability Statement

The data that support the findings of this study are available from the corresponding author upon reasonable request.

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On the Temperature Behavior of Optical Gap in Arsenic Sulfide Glasses

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On the Temperature Behavior of Optical Gap in Arsenic Sulfide Glasses

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Conflict of Interest

Open Research

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