Alkylamines-intercalated α-zirconium phosphate as latent thermal anionic initiators
Corresponding Author
Osamu Shimomura
Department of Applied Chemistry, Osaka Institute of Technology, Ashahi-ku, Osaka, 535–8585 Japan
Correspondence to: O. Shimomura (E-mail: [email protected])Search for more papers by this authorKeisuke Maeno
Department of Applied Chemistry, Osaka Institute of Technology, Ashahi-ku, Osaka, 535–8585 Japan
Search for more papers by this authorAtsushi Ohtaka
Department of Applied Chemistry, Osaka Institute of Technology, Ashahi-ku, Osaka, 535–8585 Japan
Search for more papers by this authorCorresponding Author
Shunro Yamaguchi
Institute of Scientific and Industrial Research, Osaka University, Ibaraki, Osaka, 567-0047 Japan
Correspondence to: O. Shimomura (E-mail: [email protected])Search for more papers by this authorJunko Ichihara
Institute of Scientific and Industrial Research, Osaka University, Ibaraki, Osaka, 567-0047 Japan
Search for more papers by this authorKiyoko Sakamoto
Department of Chemistry, Osaka Sangyo University, Nakagaito, Daito, Osaka, 574–8530 Japan
Search for more papers by this authorRyôki Nomura
Department of Applied Chemistry, Osaka Institute of Technology, Ashahi-ku, Osaka, 535–8585 Japan
Search for more papers by this authorCorresponding Author
Osamu Shimomura
Department of Applied Chemistry, Osaka Institute of Technology, Ashahi-ku, Osaka, 535–8585 Japan
Correspondence to: O. Shimomura (E-mail: [email protected])Search for more papers by this authorKeisuke Maeno
Department of Applied Chemistry, Osaka Institute of Technology, Ashahi-ku, Osaka, 535–8585 Japan
Search for more papers by this authorAtsushi Ohtaka
Department of Applied Chemistry, Osaka Institute of Technology, Ashahi-ku, Osaka, 535–8585 Japan
Search for more papers by this authorCorresponding Author
Shunro Yamaguchi
Institute of Scientific and Industrial Research, Osaka University, Ibaraki, Osaka, 567-0047 Japan
Correspondence to: O. Shimomura (E-mail: [email protected])Search for more papers by this authorJunko Ichihara
Institute of Scientific and Industrial Research, Osaka University, Ibaraki, Osaka, 567-0047 Japan
Search for more papers by this authorKiyoko Sakamoto
Department of Chemistry, Osaka Sangyo University, Nakagaito, Daito, Osaka, 574–8530 Japan
Search for more papers by this authorRyôki Nomura
Department of Applied Chemistry, Osaka Institute of Technology, Ashahi-ku, Osaka, 535–8585 Japan
Search for more papers by this authorABSTRACT
The reaction of glycidyl phenyl ether (GPE) with 1-aminoalkanes-intercalated α-zirconium phosphate (α-ZrP·1-aminoalkane): 1-aminoalkanes 1-aminopropane (α-ZrP·Pr), 1-aminobutane (α-ZrP·Bu), 1-aminooctane (α-ZrP·Oct), and 1-aminohexadecane (α-ZrP·Hed) was carried out at varying temperatures for 1 h periods. Reaction progress was not observed until the reactants were heated to 80 °C or above. On increasing the temperature, the conversion factors increased such that, at 140 °C, conversions of 62% (α-ZrP·Pr), 60% (α-ZrP·Bu), 67% (α-ZrP·Oct), and 64% (α-ZrP·Hed) were obtained. The thermal stabilities as latent initiators were tested: GPEs reacted with α-ZrP·Pr, α-ZrP·Bu, and α-ZrP·Oct at 40 °C for 360 h achieved conversions of 83, 55, and 59%, respectively. In contrast, the reaction in the presence of α-ZrP·Hed did not proceed at 40 °C. The order of the thermal stability of GPE in the presence of α-ZrP·1-aminoalkane intercalation compounds was: α-ZrP·Hed > α-ZrP·Bu ≈ α-ZrP·Oct > α-ZrP·Pr. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014, 52, 1854–1861
Supporting Information
Additional Supporting Information may be found in the online version of this article.
| Filename | Description |
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| pola27191-sup-0001-suppfig1.docx4.5 MB | Supplementary Information Figure 1. |
| pola27191-sup-0002-suppfig2.docx94 KB | Supplementary Information Figure 2. |
| pola27191-sup-0003-suppfig3.docx111.8 KB | Supplementary Information Figure 3. |
| pola27191-sup-0004-suppfig4.docx120.3 KB | Supplementary Information Figure 4. |
| pola27191-sup-0005-suppinfo1.docx17.7 KB | Supplementary Information |
| pola27191-sup-0006-suppinfo2.docx4.8 MB | Supplementary Information |
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