Fluorinated AB diblock copolymers and their aggregates in organic solvents
Yin-Ning Zhou
Department of Chemical and Biochemical Engineering, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, People's Republic of China
Search for more papers by this authorHua Cheng
Department of Chemical and Biochemical Engineering, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, People's Republic of China
Search for more papers by this authorCorresponding Author
Zheng-Hong Luo
Department of Chemical and Biochemical Engineering, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, People's Republic of China
Department of Chemical and Biochemical Engineering, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, People's Republic of ChinaSearch for more papers by this authorYin-Ning Zhou
Department of Chemical and Biochemical Engineering, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, People's Republic of China
Search for more papers by this authorHua Cheng
Department of Chemical and Biochemical Engineering, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, People's Republic of China
Search for more papers by this authorCorresponding Author
Zheng-Hong Luo
Department of Chemical and Biochemical Engineering, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, People's Republic of China
Department of Chemical and Biochemical Engineering, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, People's Republic of ChinaSearch for more papers by this authorAbstract
This investigation reported the preparation of fluorinated and nonamphiphilic well-defined poly(styrene)-block-poly(2,2,3,3,4,4,4-heptafluorobutyl methacrylate) (PS-b-PHFBMA) diblock copolymers via atom transfer radical polymerization (ATRP). Their chemical composition, structure, and bulk morphology were thoroughly investigated. In addition, their self-assembly behavior in a dilute organic mixture solution was investigated. It was found that that the ATRP could be used to prepare the well-defined fluorinated and nonamphiphilic PS-b-PHFBMA diblock copolymers in a controlled manner. The results also showed that abundant morphologies including sphere, worm-like structure, and vesicle could be formed with different volume ratios of these two solvents, which proves that the nonamphiphilic fluorinated diblock copolymers can self-assemble in a dilute solution, and the aforementioned reason for self-assembly was also discussed preliminarily in this work. Finally, the effect of temperature on the aggregates was investigated to verify whether the self-assembly behavior was to some extent temperature sensitive. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011
REFERENCES AND NOTES
- 1 Hirao, A.; Sugiyama, K.; Yokoyama, H. Prog Polym Sci 2007, 32, 1393–1438.
- 2 Hansen, N. M. L.; Jankova, K.; Hvilsted, S. Eur Polym J 2007, 43, 255–293.
- 3 Saïdi, S; Guittard, F; Guimon, C; Géribaldi, S. J Polym Sci Part A: Polym Chem 2005, 43, 3737–3747.
- 4 Hansen, N. M. L.; Gerstenberg, M; Haddleton, D. M.; Hvilsted, S. J Polym Sci Part A: Polym Chem 2008, 46, 8097–8111.
- 5 Reisinger, J. J.; Hillmyer, M. A. Prog Polym Sci 2002, 27, 971–1005.
- 6 Sokol, N.; Patric, J.; Niels, B. L.; Kristoffer, A. Langmuir 1999, 15, 3859–3865.
- 7 Krafft. M. P. J Polym Sci Part A: Polym Chem 2006, 44, 4251–4258.
- 8 Martinelli, E.; Fantoni, C.; Gallot, B.; Glisenti, A.; Galli, G. Macromol Symp 2010, 296, 294–302.
- 9 Percec, V.; Schlueter, D.; Kwon, Y. K.; Blackwell, J.; Moller, M.; Slangen, P. J. Macromolecules 1995, 28, 8807–8818.
- 10 Johansson, G.; Percec, V.; Ungar, G.; Smith, K. Chem Mater 1997, 9, 164–175.
- 11 Percec, V.; Johansson, G.; Ungar, G.; Zhou, J. P. J Am Chem Soc 1996, 118, 9855–9866.
- 12 Percec, V.; Ungar, G. Macromolecules 1997, 30, 645–648.
- 13 Hadson, S. D.; Jung, H.-T.; Percec, V.; Cho, W.-D.; Johansson, G.; Ungar, G.; Balagurusamy, V. K. S. Science 1997, 278, 449–452.
- 14 Percec, V.; Glodde, M.; Bera, T. K.; Miura, Y.; Shiyanovskaya, I.; Singer, K. D.; Balagurusamy, V. K. S.; Heiney, P. A.; Schnell, I.; Rapp, A.; Spiess, H.-W.; Hudson, S. D.; Duan, H. Nature 2002, 417, 384–387.
- 15 Dukeson, D. R.; Ungar, G.; Balagurusamy, V. K. S.; Percec, V.; Johansson, G. A.; Glodde, M. J Am Chem Soc 2003, 125, 15974–15980.
- 16 Percec, V.; Glodde, M.; Johansson, G.; Balagurusamy, V. K. S.; Heiney, P. A. Angew Chem Int Ed Engl 2003, 42, 4338–4342.
- 17 Percec, V.; Imam, M. R.; Bera, T. K.; Balagurusamy, V. K. S.; Peterca, M.; Heiney, P. A. Angew Chem Int Ed Engl 2005, 44, 4739–4745.
- 18 Percec, V.; Glodde, M.; Peterca, M.; Rapp, A.; Schnell, I.; Spiess, H. -W.; Bera, T. K.; Miura, Y.; Balagurusamy, V. K. S.; Aqad, E.; Heiney, P. A. Chem Eur J 2006, 12, 6298–6314.
- 19 Percec, V.; Aqad, E.; Peterca, M.; Imam, M.; Glodde, M.; Bera, T.; Miura, Y.; Balagurusamy, V.; Ewbank, P.; Wuthner, F.; Heiney, P. Chem Eur J 2007, 13, 3330–3345.
- 20 Wilson, C. J.; Wilson, D. A.; Feiring, A. E.; Percec, V. J Polym Sci Part A: Polym Chem 2010, 48, 2498–2508.
- 21 Percec, V.; Lee, M. J Macromol Sci Pure Appl Chem A 1992, 29, 723–740.
- 22 Hou, Y. X.; Tulevski, G. S.; Valint, P. L.; Gardella, J. A. Macromolecules 2002, 35, 5953–5962.
- 23 Webster, O. W. J Polym Sci Part A: Polym Chem 2000, 38, 2855–2860.
- 24
Kennedy, J. P.
J Polym Sci Part A: Polym Chem
1999,
37,
2285–2293.
10.1002/(SICI)1099-0518(19990715)37:14<2285::AID-POLA1>3.0.CO;2-P CAS Web of Science® Google Scholar
- 25
Betts, D.;
Johnson, T.;
LeRoux, D.;
DeSimone, J. M.
Controlled Radical Polymerization,
ACS Symposion Series,
1998;
Chapter 25,
418–432.
10.1021/bk-1998-0685.ch025 Google Scholar
- 26 Liu, C. C.; He, J. J.; Zhao, Q.; Zhang, M. Z.; Ni, P. H. J Polym Sci Part A: Polym Chem 2009, 47, 2702–2712.
- 27 Menghetti, M. S.; Galli, G.; Glisenti, A.; Krishnan, S.; Paik, M. Y.; Ober, C. K.; Smilgies, D. M.; Fischer, D. A. J Polym Sci Part A: Polym Chem 2009, 47, 267–284.
- 28 Rosen, B. M.; Percec, V. Chem Rev 2009, 109, 5069– 5119.
- 29 Otsu, T.; Yoshida, M.; Tazaki, T. Makromol Rapid Commun 1982, 3, 133–136.
- 30 Hawker, C. J.; Bosman, A. W.; Harth, E. Chem Rev 2001, 101, 3661–3688.
- 31 Ma, Z.; Lacroix-Desmazes, P. J Polym Sci Part A: Polym Chem 2004, 42, 2405–2415.
- 32 Ouchi, M.; Terashima, T.; Sawamoto, M. Chem Rev 2009, 109, 4963–5050.
- 33 Percec, V.; Barboiu, B. Macromolecules 1995, 28, 7970–7972.
- 34 Percec, V.; Guliashvili, T.; Ladislaw, J. S.; Wistrand, A.; Stjerndahl, A.; Sienkowska, M. J.; Monteiro, M. J.; Sahoo, S. J Am Chem Soc 2006, 128, 14156–14165.
- 35 Lligadas, G.; Percec, V. J Polym Sci Part A: Polym Chem 2008, 46, 3174–3181.
- 36 Wang, J. S.; Matyjaszewski, K. Macromolecules 1995, 28, 7901–7910.
- 37 Kato, M.; Kamigaito, M.; Sawamoto, M.; Higashimura, T. Macromolecules 1995, 28, 1721–1723.
- 38 Matyjaszewski, K.; Xia, J. H. Chem Rev 2001, 101, 2921–2990.
- 39 Kamigato, M.; Ando, T.; Sawamoto, M. Chem Rev 2001, 101, 3689–3745.
- 40 Nguyen, N. H.; Rosen, B. M.; Jiang, X.; Fleischmann, S.; Percec, V. J Polym Sci Part A: Polym Chem 2009, 47, 5577–5590.
- 41 Jiang, X.; Fleischmann, S.; Nguyen, N. H.; Rosen, B. M.; Percec, V. J Polym Sci Part A: Polym Chem 2009, 47, 5591–5605.
- 42 Zhang, Z. B.; Ying, S. K.; Shi, Z. Q. Polymer 1999, 40, 5439–5444.
- 43 Radhakrishnan, K.; Switek, K. A.; Hillmyer. M. A. J Polym Sci Part A: Polym Chem 2004, 42, 853–861.
- 44 Martinelli, E.; Agostini, S.; Galli, G.; Chiellini, E.; Glisenti, A.; Pettitt, M. E.; Callow, M. E.; Callow, J. A.; Graf, K.; Bartels, F. W. Langmuir 2008, 24, 13138–13147.
- 45 Percec, V.; Ahn, C. H.; Ungar, G.; Yeardley, D. J. P.; Moller, M.; Sheiko, S. S. Nature 1998, 391, 161–164.
- 46 Percec, V.; Dulcey, A. E.; Balagurusamy, V. S. K.; Miura, Y.; Smidrkal, J.; Peterca, M.; Nummelin, S.; Edlund, U.; Hudson, S. D.; Heiney, P. A.; Hu, D. A.; Magonov, S. N.; Vinogradov, S. A. Nature 2004, 430, 764–768.
- 47 Sutton, D.; Nasongkla, N.; Blanco, E.; Gao, J. M. Pharm Res 2007, 24, 1029–1046.
- 48 Berret, J. F.; Schonbeck, N.; Gazeau, F.; Kharrat, D. E.; Sandre, O.; Vacher, A.; Airiau, M. J Am Chem Soc 2006, 128, 1755–1761.
- 49 Ge, Z. S.; Xie, D.; Chen, D. Y.; Jiang, X. Z.; Zhang, Y. F.; Liu, H. W.; Liu, S. Y. Macromolecules 2007, 40, 3538–3546.
- 50 Rosen, B. M.; Wilson, C. J.; Wilson, D. A.; Peterca, M.; Imam, M. R.; Percec, V. Chem Rev 2009, 109, 6275–6540.
- 51 Darling, S. B. Prog Polym Sci 2007, 32, 1152–1204.
- 52 Percec, V.; Rudick, J. G.; Peterca, M.; Aqad, E.; Imam, M. R.; Heiney, P. A.; Paul, A. J Polym Sci Part A: Polym Chem 2007, 45, 4974–4987.
- 53 Imam, M. R.; Peterca, M.; Edlund, U.; Balagurusamy, V. S. K.; Percec, V. J Polym Sci Part A: Polym Chem 2009, 47, 4165–4193.
- 54 Percec, V.; Wilson, D. A.; Leowanawat, P.; Wilson, C. J.; Hughes, A. D.; Kaucher, M. S.; Hammer, D. A.; Levine, D. H.; Kim, A. J.; Bates, F. S.; Davis, K. P.; Lodge, T. P.; Klein, M. L.; DeVane, R. H.; Aqad, E.; Rosen, B. M.; Argintaru, A. O.; Sienkowska, M. J.; Rissanen, K.; Nummelin, S.; Ropponen, J. Science 2010, 328, 1009–1014.
- 55 Korczagin, I.; Hempenius, M. A.; Fokkink, R. G.; Stuart, M. A. C.; Al-Hussein, M.; Bomans, P. H. H.; Frederik, P. M.; Vancso, G. J. Macromolecules 2006, 39, 2306–2315.
- 56 Keller, R. N.; Wycoff, H. D. Inorg Synth 1947, 2, 47–73.
- 57 Kotula, I.; Marciniak, B. J Chem Eng Data 2001, 46, 783–790.
- 58 Zhang, W. Q.; Shi, L. Q.; An, Y. L.; Gao, L. C.; Wu, K.; Ma, R. J.; Zhang, B. H. Macromol Chem Phys 2004, 205, 2017–2025.
- 59 MediaFire, Handbook of Solvents; Available at: http://www.mediafire.com/?wmmojttqnx2, December, 2007.
- 60 Matyjaszewski, K.; Shipp, D. A.; Wang, J. L.; Grimaud, T.; Patten, T. E. Macromolecules 1998, 31, 6836–6840.
- 61 Qiu, J. J.; Luo, Z. H. J Polym Sci Part A: Polym Chem 2011, 49, 2513–2519.
- 62 Zhang, L.; Eisenberg, A. J Am Chem Soc 1996, 118, 3168–3181.
- 63
Zhang, L.;
Eisenberg, A.
Polym Adv Technol
1998,
9,
677–699.
10.1002/(SICI)1099-1581(1998100)9:10/11<677::AID-PAT845>3.0.CO;2-# CAS Web of Science® Google Scholar
