Volume 28, Issue 11 pp. 3165-3178
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Aspects of the thermal properties of poly(2-vinyl anthraquinone)

A. J. Gradwell

A. J. Gradwell

Department of Colour Chemistry, University of Leeds, Leeds, LS2 9JT, United Kingdom

Warwick International PLC., Chemicals Div. Mostyn, Clwyd, CH8 9HE, United Kingdom.

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J. T. Guthrie

Corresponding Author

J. T. Guthrie

Department of Colour Chemistry, University of Leeds, Leeds, LS2 9JT, United Kingdom

Department of Colour Chemistry, University of Leeds, Leeds, LS2 9JT, United KingdomSearch for more papers by this author
A. Kazlauciunas

A. Kazlauciunas

Department of Colour Chemistry, University of Leeds, Leeds, LS2 9JT, United Kingdom

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First published: October 1990
Citations: 4

Abstract

2-Vinyl anthraquinone was synthesized as described previously. In this article, three approaches to polymerization of 2-vinyl anthraquinone are examined bulk thermal, chemical, and γ-radiation-induced. Polymerization in both the bulk phase and in solution were attempted. Thermal characterization has been carried out using differential scanning calorimetry (DSC), x-ray diffraction (XRD), scanning electron microscopy (SEM) and hot-stage optical microscopy (HSOM). Thermogravimetric analysis (TGA) has been used to provide procedural “apparent” activation energies for decomposition of the polymer.

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