Volume 25, Issue 11 pp. 1356-1365

Special issue: Research article

An s-triazine briged silylalkyl sol–gel precursor—synthesis, structure and coating formation for electrical insulation of copper wire and corrosion protection of construction steel^†

Stefan Pfeifer,

Stefan Pfeifer

Institute of Inorganic Chemistry, TU Bergakademie Freiberg, Leipziger Str. 29, D-09596 Freiberg, Germany

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Alejandro Gutierrez,

Alejandro Gutierrez

Van Loon Chemical Innovation, Science Park 408, 1098 XH Amsterdam, The Netherlands

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Edwin Kroke,

Corresponding Author

Edwin Kroke

Institute of Inorganic Chemistry, TU Bergakademie Freiberg, Leipziger Str. 29, D-09596 Freiberg, Germany

Correspondence to: Edwin Kroke, Institute of Inorganic Chemistry, TU Bergakademie Freiberg, Leipziger Str. 29, D-09596 Freiberg, Germany.

E-mail: [email protected]

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Stefan Pfeifer,

Stefan Pfeifer

Institute of Inorganic Chemistry, TU Bergakademie Freiberg, Leipziger Str. 29, D-09596 Freiberg, Germany

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Alejandro Gutierrez,

Alejandro Gutierrez

Van Loon Chemical Innovation, Science Park 408, 1098 XH Amsterdam, The Netherlands

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Edwin Kroke,

Corresponding Author

Edwin Kroke

Institute of Inorganic Chemistry, TU Bergakademie Freiberg, Leipziger Str. 29, D-09596 Freiberg, Germany

Correspondence to: Edwin Kroke, Institute of Inorganic Chemistry, TU Bergakademie Freiberg, Leipziger Str. 29, D-09596 Freiberg, Germany.

E-mail: [email protected]

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First published: 25 August 2014

https://doi.org/10.1002/pat.3379

Citations: 3

^†

This article is published in Journal of Polymers for Advanced Technologies as a special issue on 12th PAT Conference in Berlin, 2013, edited by Prof. Andreas Lendlein and Prof. Marc Behl, Institute of Biomaterial Science, Helmholtz-Zentrum Geesthacht GmbH, Centre for Materials and Coastal Research, Kantstr. 55, 14513 Teltow, Germany.

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Abstract

An aminoalkylalkoxysilane modified s-triazine was prepared and used as single-source precursor for hybrid coatings. These coating materials were applied and tested for the electrical insulation of fine copper wires and for corrosion protection of construction steel. The molecular precursor was comprehensively analyzed using FT-IR, ¹H, ¹³C and ²⁹Si NMR spectroscopy. Besides, the initial stages of hydrolysis and condensation reactions under acidic conditions were examined with solution ²⁹Si NMR spectroscopy. Structures of gelled and heat-treated samples were analyzed with CP/MAS ²⁹Si NMR and FT-IR spectroscopy. Sols were applied on fine copper wires using industrial coating and curing techniques. The performance of the hybrid coatings was characterized by electrical breakdown tests, pinhole tests and mechanical strength measurements. The anti-corrosion behavior of the s-triazine precursor derived coatings on steel substrates was studied by electrical impedance spectroscopy. The spectra were interpreted with respect to different hydrolysis and condensation rates, curing temperatures and coating thicknesses. Copyright © 2014 John Wiley & Sons, Ltd.

REFERENCES

1 D. Avnir, L. C. Klein, D. Levy, U. Schubert, A. B. Wojcik, Chem. Org. Silicon Compd. 1998, 2, 2317.
10.1002/0470857250.ch40
CAS Google Scholar
2 S. Pfeifer, A. Schwarzer, D. Schmidt, E. Brendler, M. Veith, E. Kroke, New J. Chem. 2013, 37, 169.
10.1039/C2NJ40538E
CAS Web of Science® Google Scholar
3 T. Ogoshi, Y. Chujo, Compos. Interfaces 2005, 11, 539.
10.1163/1568554053148735
CAS Web of Science® Google Scholar
4 I. C. Schrotter, M. Smahi, C. Guizard, J. Appl. Polym. Sci. 1996, 61, 2137.
10.1002/(SICI)1097-4628(19960919)61:12<2137::AID-APP12>3.0.CO;2-4
CAS Web of Science® Google Scholar
5 G. Ragosta, P. Musto, Polym. Lett. 2009, 3, 413.
10.3144/expresspolymlett.2009.51
CAS Web of Science® Google Scholar
6 J. Ayres, W. H. Simendinger, C. M. Balik, J. Coat. Technol. Res. 2007, 4, 463.
10.1007/s11998-007-9054-8
CAS Web of Science® Google Scholar
7 C. J. Brinker, G. W. Scherer, Sol-Gel-Science -The Physics and Chemistry of Sol-Gel Processing, Academic Press, Boston, 1990.
Google Scholar
8 U. Schubert, J. Mater. Chem. 2005, 15, 701.
10.1039/b504269k
CAS Web of Science® Google Scholar
9 B. Tyagi, K. Sidhpuria, B. Shaik, R. V. Jasra, Ind. Eng. Chem. Res. 2006, 45, 8643.
10.1021/ie060519p
CAS Web of Science® Google Scholar
10 K. A. Andrianov, T. V. Vasileva, N. M. Katashuk, T. V. Snigireva, B. I. Dychenko, Polym. Sci. 1976, 18, 1457.
Google Scholar
11 C. L. Roux , H. Yang , S. Wenzel , S. Grigoras , M. A. Brook, Organometallics 1998, 17, 556.
10.1021/om970953e
Web of Science® Google Scholar
12 G. Kickelbick, Hybrid Materials: Synthesis, Characterization, and Applications, Wiley-VCH, Weinheim, 2007.
Google Scholar
13 C. Elschenbroich, Organometallics, Wiley-VCH, Weinheim, 2006.
Google Scholar
14 S. Pfeifer, E. Brendler, M. Veith, E. Kroke, J. Sol-Gel Sci. Technol. 2014, 70, 191.
10.1007/s10971-014-3343-3
CAS Web of Science® Google Scholar
15 W. Henry, J. Oviatt, K. J. Shea , J. H. Small, Chem. Mater. 1993, 5, 943.
10.1021/cm00031a012
Web of Science® Google Scholar
16 H. Saito, Y. Nishio, M. Kobayashi , Y. Sugahara, J. Sol-Gel Sci. Technol. 2011, 57, 51.
10.1007/s10971-010-2323-5
CAS Web of Science® Google Scholar
17 R. J. P. Corriu, D. Leclercq, Angew. Chem. Int. Ed. Engl. 1996, 35, 1421.
10.1002/anie.199614201
CAS Web of Science® Google Scholar
18 K. J. Shea, D. A. Loy, Chem. Mater. 1989, 1, 572.
10.1021/cm00006a003
CAS Web of Science® Google Scholar
19 T. J. Mooibroek, P. Gamez, Inorg. Chim. Acta 2007, 360, 381.
10.1016/j.ica.2006.07.061
CAS Web of Science® Google Scholar
20 V. R. Pedireeddi, D. Belhekar, Tetrahedron 2002, 58, 2937.
10.1016/S0040-4020(02)00202-8
Web of Science® Google Scholar
21 S. Cicchi, G. Ghini, S. Fallani, A. Brandi, D. Berti, F. Betti, P. Baglioni, Tetrahedron Lett. 2008, 49, 1701.
10.1016/j.tetlet.2007.12.124
CAS Web of Science® Google Scholar
22 A. Gams, G. Widmer, W. Fisch, Helv. Chim. Acta 1994, 24, 302.
10.1002/hlca.19410240232
Google Scholar
23 I. Arafa, M. Shatnawi, H. Saad, J. Solid State Chem. 2009, 182, 2167.
10.1016/j.jssc.2009.05.037
CAS Web of Science® Google Scholar
24 N. E. A. El-Gamel, M. Schwarz, E. Brendler, E. Kroke, Chem. Commun. 2006, 4741.
10.1039/B609349C
CAS PubMed Web of Science® Google Scholar
25 J.-W. Kang, D.-S. Lee, H.-D. Park, Y.-S. Park, J. W. Kim, W.-I. Jeong, K.-M. Yoo, K. Go, S.-H. Kim, J.-J. Kim, J. Mater. Chem. 2007, 17, 3714.
10.1039/b705741e
CAS Web of Science® Google Scholar
26 A. Hou, H. Chen, Mater. Sci. Eng. B 2010, 167, 124.
10.1016/j.mseb.2010.01.065
CAS Web of Science® Google Scholar
27 K. Xie, Y. Yu, Y. Shi, Carbohydr. Polym. 2009, 78, 799.
10.1016/j.carbpol.2009.06.019
CAS Web of Science® Google Scholar
28 N. Lin, H. Li, Y. Wang, Y. Feng, D. Qin, Q. Gan, S. Chen, Eur. J. Inorg. Chem. 2008, 4781.
10.1002/ejic.200800645
CAS Web of Science® Google Scholar
29 H.-Y. Wu, Y.-H. Chen, D. Saikia, Y.-C. Pan, J. Fang, L.-D. Tsai, H.-M. Kao, J. Membr. Sci. 2013, 447, 274.
10.1016/j.memsci.2013.07.043
CAS Web of Science® Google Scholar
30 H.-Y. Wu, D. Saikia, H.-Y. Chao, Y.-C. Pan, J. Fang, L.-D. Tsai, G. T. K. Fey, H.-M. Kao, J. Power. Sources 2013, 238, 265.
10.1016/j.jpowsour.2013.03.097
CAS Web of Science® Google Scholar
31 M. B. Steffensen, E. Hollink, F. Kuschel, M. Bauer, E. E. Simanek, J. Polym. Sci. Part A: Polym. Chem. 2006, 44, 3411.
10.1002/pola.21333
CAS PubMed Web of Science® Google Scholar
32 K. Tsuchida, US 2011/0003989 A1, 2011.
Google Scholar
33 D. L. Bailey, R. M. Pike, US 2949434 160, 1996.
Google Scholar
34 G. Socrates, Infrared and Raman Characteristic Group Frequencies, Wiley, Chichester, 2001.
Web of Science® Google Scholar
35 A. Schwarzer, T. Saplinova, E. Kroke, Coord. Chem. Rev. 2013, 257, 2032.
10.1016/j.ccr.2012.12.006
CAS Web of Science® Google Scholar
36 Y. Xu , X. Sun, D. Wu, Y. Sun, Y. Yang, H. Yuan, F. Deng, Z. Wu, J. Solution Chem. 2007, 36, 327.
10.1007/s10953-006-9117-y
CAS Web of Science® Google Scholar
37 M. Asomoza, M. P. Dominguez, S. Solis, V. H. Lara, P. Bosch, T. Lopez, Mater. Lett. 1998, 36, 249.
10.1016/S0167-577X(98)00043-3
CAS Web of Science® Google Scholar
38 I. Artaki, T. W. Zerda, J. Jonas, Mater. Lett. 1985, 3, 493.
10.1016/0167-577X(85)90097-7
CAS Web of Science® Google Scholar
39 I. Artaki, T. W. Zerda, J. Jonas, Mater. Lett. 1986, 81, 381.
CAS Web of Science® Google Scholar
40 A. H. Boonstra, T. N. M. Bernards, J. J. T. Smits, J. Non-Cryst. Solids 1989, 109, 141.
10.1016/0022-3093(89)90026-4
CAS Web of Science® Google Scholar
41 A. H. Boonstra, J. M. E. Baken, J. Non-Cryst. Solids 1990, 122, 171.
10.1016/0022-3093(90)91063-W
CAS Web of Science® Google Scholar
42 M. G. Voronkov, Yu A. Yuzhelevskii, V. P. Mileshkevich, Russ. Chem. Rev. 1975, 44, 355.
10.1070/RC1975v044n04ABEH002273
Google Scholar
43 R. K. Ile, The Chemistry of Silica, Wiley, New York, 1979.
Google Scholar
44 W. Stöber, A. Fink, E. Bohn, J. Colloid Interface Sci. 1968, 26, 62.
10.1016/0021-9797(68)90272-5
CAS Web of Science® Google Scholar
45 G. H. Bogush, M. A. Tracy, C. F. Zukoski, J. Non-Cryst. Solids 1988, 104, 95.
10.1016/0022-3093(88)90187-1
CAS Web of Science® Google Scholar
46 R. J. Hook, J. Non-Cryst. Solids 1996, 195, 1.
10.1016/0022-3093(95)00508-0
CAS Web of Science® Google Scholar
47 V. Bennevault-Celton, O. Maciejak, B. Desmazières, H. Cheradame_, Polym. Int. 2010, 59, 1273.
10.1002/pi.2863
CAS Web of Science® Google Scholar
48 Y. Sugahara, S. Okada, K. Kuroda, C. Kato, J. Non-Cryst. Solids 1992, 139, 25.
10.1016/S0022-3093(05)80802-6
CAS Web of Science® Google Scholar
49 Z. Zhang, B. P. Gormann, H. Dong, R. A. Orozco-Teran, J. Sol-Gel Sci. Technol. 2003, 28, 159.
10.1023/A:1026098729993
CAS Web of Science® Google Scholar
50 M. Kendig, J. Scully, Corrosion 1990, 46, 22.
10.5006/1.3585061
CAS Web of Science® Google Scholar
51 A. Amirudin, D. Thierry, Prog. Org. Coat. 1995, 26, 1.
10.1016/0300-9440(95)00581-1
CAS Web of Science® Google Scholar
52 D. C. Silverman, Corrosion 1990, 46, 589.
10.5006/1.3585153
CAS Web of Science® Google Scholar
53 W. M. Bos, Prediction of coating durability, early detection using electrochemical methods. PhD thesis, TU Delft, the Netherlands, 2008.
Google Scholar
54 I. Epelboin, M. Keddam, H. Takenouti, J. Appl. Electrochem. 1972, 2, 71.
10.1007/BF00615194
CAS Google Scholar
55 R. Winston Revive, D. C. Silverman, Corrosion 1988, 44, 280.
10.5006/1.3583938
Google Scholar
56 DIN EN. 60851-2:2010-08, 2010.
Google Scholar
57 DIN EN. 60851-5:2005-04, 2005.
Google Scholar
58 DIN EN. 60851-3:2009-12, 2009.
Google Scholar

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Volume25, Issue11

Special Issue:From macromolecules to materials to systems

November 2014

Pages 1356-1365

An s-triazine briged silylalkyl sol–gel precursor—synthesis, structure and coating formation for electrical insulation of copper wire and corrosion protection of construction steel^†

Abstract

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An s-triazine briged silylalkyl sol–gel precursor—synthesis, structure and coating formation for electrical insulation of copper wire and corrosion protection of construction steel†

Abstract

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An s-triazine briged silylalkyl sol–gel precursor—synthesis, structure and coating formation for electrical insulation of copper wire and corrosion protection of construction steel^†