Volume 138, Issue 1 pp. 111-116
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Polymerisation of intercalated solvents in gels; An attempt to obtain molecular blending

Tosca Corstjens

Tosca Corstjens

Eindhoven University of Technology/The Dutch Polymer Institute (DPI), P.O. Box 513, 5600 MB Eindhoven, The Netherlands

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Sanjay Rastogi

Corresponding Author

Sanjay Rastogi

Eindhoven University of Technology/The Dutch Polymer Institute (DPI), P.O. Box 513, 5600 MB Eindhoven, The Netherlands

Eindhoven University of Technology/The Dutch Polymer Institute (DPI), P.O. Box 513, 5600 MB Eindhoven, The NetherlandsSearch for more papers by this author
Piet Lemstra

Piet Lemstra

Eindhoven University of Technology/The Dutch Polymer Institute (DPI), P.O. Box 513, 5600 MB Eindhoven, The Netherlands

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First published: 04 March 2011
Citations: 2

Abstract

Recent studies performed on gels like syndiotactic polystyrene/benzylmethacrylate and poly-benzyl-L-glutamate/benzylmethacrylate indicate that the solvent molecules can be intercalated between or within the helices of the polymer. The present paper describes the UV polymerisation of these intercalated solvents. It was found that for both systems the solvent stays intercalated between the helices after polymerisation. This method can therefore be used to blend two immiscible polymers on a molecular scale.

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