Volume 42, Issue 17 2100305
Research Article

Novel Polymer-Based Organic/c-Si Monolithic Tandem Solar Cell: Enhanced Efficiency using Interlayer and Transparent Top Electrode Engineering

HyunJung Park

HyunJung Park

Institute for Energy Research, Korea University, Seoul, 02841 Republic of Korea

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So Hyun Park

So Hyun Park

Advanced Photovoltaics Research Center, Korea Institute of Science and Technology, Seoul, 02792 Republic of Korea

Energy and Environment Policy and Technology, Graduate School of Energy and Environment (KU-KIST Green School), Korea University, Seoul, 02841 Republic of Korea

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Sang-Won Lee

Sang-Won Lee

Department of Materials Science and Engineering, Korea University, Seoul, 02841 Republic of Korea

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Yoonmook Kang

Yoonmook Kang

Energy and Environment Policy and Technology, Graduate School of Energy and Environment (KU-KIST Green School), Korea University, Seoul, 02841 Republic of Korea

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Donghwan Kim

Donghwan Kim

Department of Materials Science and Engineering, Korea University, Seoul, 02841 Republic of Korea

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Hae Jung Son

Corresponding Author

Hae Jung Son

Advanced Photovoltaics Research Center, Korea Institute of Science and Technology, Seoul, 02792 Republic of Korea

Energy and Environment Policy and Technology, Graduate School of Energy and Environment (KU-KIST Green School), Korea University, Seoul, 02841 Republic of Korea

E-mail: [email protected]; [email protected]

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Hae-Seok Lee

Corresponding Author

Hae-Seok Lee

Energy and Environment Policy and Technology, Graduate School of Energy and Environment (KU-KIST Green School), Korea University, Seoul, 02841 Republic of Korea

E-mail: [email protected]; [email protected]

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First published: 04 August 2021
Citations: 3

Abstract

Tandem solar cells which are electrically connected with various photoactive materials have the potential to solve the current challenges by exceeding the theoretically limited efficiency of single junction solar cells. Here the first monolithic organic/silicon tandem cell is reported based on a semitransparent polymer on a crystalline silicon (c-Si) substrate. Herein, experimental results are presented for four-terminal (4-T) and monolithic two-terminal (2-T) organic/c-Si tandem cells using organic cells with an inverted n-i-p structure and c-Si cells with an n-type TOPCon structure with detailed analysis. The best 4-T tandem cell efficiency is 15.22%, and 2-T results show that the top (organic) and bottom (c-Si) cells are electrically connected by an open-circuit voltage over 1.4 V. Further, a simulated efficiency of over 20% using the organic/c-Si tandem is achieved, implying the tandem efficiency can be enhanced through further improvement of electric and optical characteristics with the optimization.

Conflict of Interest

The authors declare no conflict of interest.

Data Availability Statement

Research data are not shared.

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