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Studies on the polymerization of ethylene using a high-yield MgCl2-supported titanium catalyst, 4†. Structural investigation by X-ray diffraction and electron spin resonance measurements on the state of titanium ions in the standard system and its modifications‡
Hans Fuhrmann,
Werner Herrmann,
Corresponding Author
Hans Fuhrmann
Institut für Organische Katalyseforschung an der Universität Rostock e.V., 18055 Rostock, Buchbinderstraß 5-6, Germany
Institut für Organische Katalyseforschung an der Universität Rostock e.V., 18055 Rostock, Buchbinderstraß 5-6, GermanySearch for more papers by this authorWerner Herrmann
Bundesanstalt für Materialforschung und -prüfung (BAM), 12489 Berlin, Rudower Chaussee 5
Search for more papers by this authorHans Fuhrmann,
Werner Herrmann,
Corresponding Author
Hans Fuhrmann
Institut für Organische Katalyseforschung an der Universität Rostock e.V., 18055 Rostock, Buchbinderstraß 5-6, Germany
Institut für Organische Katalyseforschung an der Universität Rostock e.V., 18055 Rostock, Buchbinderstraß 5-6, GermanySearch for more papers by this authorWerner Herrmann
Bundesanstalt für Materialforschung und -prüfung (BAM), 12489 Berlin, Rudower Chaussee 5
Search for more papers by this author†
Part 3: cf. ref.10
‡
Dedicated to Prof. Dr. rer. nat., Dr.-Ing. E. h. Hansjörg Sinn with best wishes on the occasion of his 65th birthday
Abstract
The MgCl2-supported titanium catalyst MTKST was characterized by X-ray diffraction measurement and electron spin resonance (ESR) spectroscopy. To obtain a better understanding of the nature of active sites the process of catalyst formation was interrupted at several stages to obtain samples for ESR measurements. Likewise some systematic modifications of the standard system were performed and the results were studied by ESR technique. The structural data were correlated with the activity pattern in the polymerization of ethylene. It is suggested that the precursor of an active site is a clustered titanium species containing titanium ions of mixed valence state which is complexed and alkylated by AIR3 giving a polymerization active species of high efficiency. A comparison with the polymerization data suggests that the active species or its immediate precursor is characterized by an ESR signal with rhombic anisotropy with g1 = 1,94, g2 = 1,89, g3 = 1,76.
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