Etude de la réaction de télomérisation d'un monomère tensioactif anionique
Bernard Boutevin
Laboratoire de Chimie Appliquée—URA D 11930—Ecole Nationale Supérieure de Chimie de Montpellier—8, rue de l'Ecole Normale—34053 Montpellier Cedex 1, France
Search for more papers by this authorCorresponding Author
Jean-Jaques Robin
Laboratoire de Chimie Appliquée—URA D 11930—Ecole Nationale Supérieure de Chimie de Montpellier—8, rue de l'Ecole Normale—34053 Montpellier Cedex 1, France
Laboratoire de Chimie Appliquée—URA D 11930—Ecole Nationale Supérieure de Chimie de Montpellier—8, rue de l'Ecole Normale—34053 Montpellier Cedex 1, FranceSearch for more papers by this authorBernard Boyer
Laboratoire de Chimie Organique Physique—Université de Montpellier II—Place Eugène Bataillon—34095 Montpellier Cedex 5, France
Search for more papers by this authorJean-Pierre Roque
Laboratoire de Chimie Organique Physique—Université de Montpellier II—Place Eugène Bataillon—34095 Montpellier Cedex 5, France
Search for more papers by this authorOmar Senhaji
Laboratoire de Chimie Organique Physique—Université de Montpellier II—Place Eugène Bataillon—34095 Montpellier Cedex 5, France
Search for more papers by this authorBernard Boutevin
Laboratoire de Chimie Appliquée—URA D 11930—Ecole Nationale Supérieure de Chimie de Montpellier—8, rue de l'Ecole Normale—34053 Montpellier Cedex 1, France
Search for more papers by this authorCorresponding Author
Jean-Jaques Robin
Laboratoire de Chimie Appliquée—URA D 11930—Ecole Nationale Supérieure de Chimie de Montpellier—8, rue de l'Ecole Normale—34053 Montpellier Cedex 1, France
Laboratoire de Chimie Appliquée—URA D 11930—Ecole Nationale Supérieure de Chimie de Montpellier—8, rue de l'Ecole Normale—34053 Montpellier Cedex 1, FranceSearch for more papers by this authorBernard Boyer
Laboratoire de Chimie Organique Physique—Université de Montpellier II—Place Eugène Bataillon—34095 Montpellier Cedex 5, France
Search for more papers by this authorJean-Pierre Roque
Laboratoire de Chimie Organique Physique—Université de Montpellier II—Place Eugène Bataillon—34095 Montpellier Cedex 5, France
Search for more papers by this authorOmar Senhaji
Laboratoire de Chimie Organique Physique—Université de Montpellier II—Place Eugène Bataillon—34095 Montpellier Cedex 5, France
Search for more papers by this authorAbstract
The synthesis of a new anionic polymerizable surfactant is described. It is obtained by reaction between methacryloyl chloride and 5-phenyl-1-pentanol. In a last step, the aromatic group is alkylated with succinic anhydride in order to obtain an ionic group. All products were characterized by 1H nuclear magnetic resonance and the transfer constant CT with C8H17C2H4SH and the ratio kp2/kt were determined. CT is in agreement with that of classical acrylates whereas kp2/kt is lower because of the long methacryloyl chain which reduces the propagation rate.
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