Kinetische analyse der copolymerisationsgeschwindigkeit von N-vinyl-2-pyrrolidon mit styrol und methylmethacrylat
Corresponding Author
Dietrich Braun
Deutsches Kunststoff-Institut, Schloßgartenstr. 6 R, 6100 Darmstadt, BRD
Deutsches Kunststoff-Institut, Schloßgartenstr. 6 R, 6100 Darmstadt, BRDSearch for more papers by this authorWojciech K. Czerwinski
Deutsches Kunststoff-Institut, Schloßgartenstr. 6 R, 6100 Darmstadt, BRD
Search for more papers by this authorCorresponding Author
Dietrich Braun
Deutsches Kunststoff-Institut, Schloßgartenstr. 6 R, 6100 Darmstadt, BRD
Deutsches Kunststoff-Institut, Schloßgartenstr. 6 R, 6100 Darmstadt, BRDSearch for more papers by this authorWojciech K. Czerwinski
Deutsches Kunststoff-Institut, Schloßgartenstr. 6 R, 6100 Darmstadt, BRD
Search for more papers by this authorAbstract
The polymerization rate of two binary monomer systems styrene (St)/N-vinyl-2-pyrrolidone (NVP) and NVP/methyl methacrylate (MMA) was investigated dilatometrically in bulk at 60°C with AIBN as initiator. While the copolymerization rate of the system St/NVP can be satisfactorily described by means of the classical reaction model, this is not the case for the system NVP/MMA. This deviation from the classical model can be explained by a charge-transfer interaction between NVP and MMA which was measured by means of 1H and 13C NMR spectroscopy.
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