Volume 19, Issue 12 2402228
Research Article

High-Performance and Low-Cost Gradient Refractive Index Films for Ultra-Broadband and Ultra-Wide Angle Antireflective Applications

Han Wu

Han Wu

Hangzhou Institute for Advanced Study, University of Chinese Academy of Sciences, Hangzhou, 310024 China

Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai, 201800 China

State key laboratory of Modern Optical Instrumentation, College of Optical Science and Engineering, Zhejiang University, Hangzhou, 310027 China

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Zhenghao Huan

Zhenghao Huan

Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai, 201800 China

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Haiqi Gao

Haiqi Gao

Hangzhou Institute for Advanced Study, University of Chinese Academy of Sciences, Hangzhou, 310024 China

Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai, 201800 China

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Haidong He

Haidong He

Hangzhou Institute for Advanced Study, University of Chinese Academy of Sciences, Hangzhou, 310024 China

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Junren Wen

Junren Wen

Hangzhou Institute for Advanced Study, University of Chinese Academy of Sciences, Hangzhou, 310024 China

Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai, 201800 China

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Yueguang Zhang

Yueguang Zhang

State key laboratory of Modern Optical Instrumentation, College of Optical Science and Engineering, Zhejiang University, Hangzhou, 310027 China

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Tao Liang

Tao Liang

Hangzhou Institute for Advanced Study, University of Chinese Academy of Sciences, Hangzhou, 310024 China

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Yifan Zheng

Yifan Zheng

Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai, 201800 China

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Yuchuan Shao

Yuchuan Shao

Shanghai Institute of Optics and Fine Mechanics, Chinese Academy of Sciences, Shanghai, 201800 China

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Weidong Shen

Corresponding Author

Weidong Shen

State key laboratory of Modern Optical Instrumentation, College of Optical Science and Engineering, Zhejiang University, Hangzhou, 310027 China

E-mail: [email protected][email protected]

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Chenying Yang

Corresponding Author

Chenying Yang

Hangzhou Institute for Advanced Study, University of Chinese Academy of Sciences, Hangzhou, 310024 China

State key laboratory of Modern Optical Instrumentation, College of Optical Science and Engineering, Zhejiang University, Hangzhou, 310027 China

E-mail: [email protected][email protected]

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First published: 19 March 2025

Abstract

Gradient refractive index (GRIN) films have great potential for applications in photovoltaics, imaging, and other fields due to their excellent antireflective ability. However, the development of highly reproducible processes for large-area GRIN film preparation remains challenging. Here, a novel method to fabricate GRIN nanoporous silica films is proposed using magnetron co-sputtering of silica-alumina composite multilayer films followed by single-step selective wet etching with phosphoric acid. The GRIN film with excellent ultra-broadband, ultra-wide angle antireflective properties (average double-sided reflection suppressed within 14.2% up to 70° for 400–2000 nm band), high reproducibility, and good environmental reliability is demonstrated. Furthermore, the photovoltaic glass covers prepared with this GRIN film are verified to help reduce the energy loss in solar cells.

Conflict of Interest

The authors declare no conflict of interest.

Data Availability Statement

The data that support the findings of this study are available from the corresponding author upon reasonable request.

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