Rate constants determined for the thermal dimerization of chlorotrifluoroethene to dichlorohexafluorocyclobutane at 404–672 K have been correlated with previously published results. For the temperature range of 404–800 K,

The dependence of the preexponential factor on temperature corresponds to a value of 17 J/K·mol for the difference in heat capacity (ΔC_p^±) between the activation complex and the reactant.

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Volume11, Issue6

June 1979

Pages 585-593

The kinetics of dimerization of chlorotrifluoroethene

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The kinetics of dimerization of chlorotrifluoroethene

Abstract

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