Metal complexes with tetrapyrrole ligands: Part LXXVII^† . New osmium complexes of the 5,10,15,20-tetrakis-(4-carboxyphenyl) porphyrin

Johann W. Buchler,

Johann W. Buchler

Institute for Inorganic Chemistry, Technical University of Darmstadt, Petersenstraße 18, D-64287 Darmstadt, Germany

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Joachim R. Simon,

Corresponding Author

Joachim R. Simon

Institute for Inorganic Chemistry, Technical University of Darmstadt, Petersenstraße 18, D-64287 Darmstadt, Germany

Dr Theodor Schuchardt & Co., Eduard-Buchner-Straße 14-20, D-85662 Hohenbrunn, GermanySearch for more papers by this author

Johann W. Buchler,

Johann W. Buchler

Institute for Inorganic Chemistry, Technical University of Darmstadt, Petersenstraße 18, D-64287 Darmstadt, Germany

Search for more papers by this author

Joachim R. Simon,

Corresponding Author

Joachim R. Simon

Institute for Inorganic Chemistry, Technical University of Darmstadt, Petersenstraße 18, D-64287 Darmstadt, Germany

Dr Theodor Schuchardt & Co., Eduard-Buchner-Straße 14-20, D-85662 Hohenbrunn, GermanySearch for more papers by this author

First published: 15 May 2001

https://doi.org/10.1002/jpp.352

^†

Part LXXVI: Ref. [ 1].

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Abstract

The synthesis and characterization of new alkali-soluble osmium tetraphenylporphyrinates, complexes of the 5,10,15,20-tetrakis(4-carboxyphenyl)porphyrin Os(tH₄cpp)L₂ and Os(tH₄cpp)LL′ (2a–j), is described. 2a–j are obtained from the corresponding new osmium porphyrinates Os(tmecpp)L₂ and Os(tmecpp)LL′ (1a–k) by alkaline saponification and precipitation with hydrochloric acid. In fact, the osmium(II) porphyrinates 2c–f as well as 2i–j are oxidized to the osmium(III) porphyrinates Os(tH₃cpp)L₂ (3c–f) and Os(tH₃cpp)LL′ (3i–j) in the presence of air, as confirmed by UV-vis spectroscopy. Copyright © 2001 John Wiley & Sons, Ltd.

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Volume5, Issue6

June 2001

Pages 500-502

Metal complexes with tetrapyrrole ligands: Part LXXVII^† . New osmium complexes of the 5,10,15,20-tetrakis-(4-carboxyphenyl) porphyrin

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Metal complexes with tetrapyrrole ligands: Part LXXVII† . New osmium complexes of the 5,10,15,20-tetrakis-(4-carboxyphenyl) porphyrin

Abstract

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Metal complexes with tetrapyrrole ligands: Part LXXVII^† . New osmium complexes of the 5,10,15,20-tetrakis-(4-carboxyphenyl) porphyrin