Reactions of the diene 1-benzyloxy-2-methoxy-1,3-pentadiene-5-ol in intramolecular Diels-Alder reactions using maleic anhydride or fumaric acid ethyl ester is described. The new reactive diene is prepared starting from 3-methoxypyridine. The structure of the diene was elucidated by a NOE nmr experiment.

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Volume29, Issue7

December 1992

Pages 1841-1845

A new diene, 2-methoxy-1,3-pentadiene-5-ol. Synthesis and intramolecular diels-alder reactions

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A new diene, 2-methoxy-1,3-pentadiene-5-ol. Synthesis and intramolecular diels-alder reactions

Abstract

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