Review
Utility of Acetylenedicarboxylate in Organic Synthesis
Essmat M. El-Sheref,
Alan B. Brown,
Corresponding Author
Essmat M. El-Sheref
Chemistry Department, Faculty of Science, Minia University, El Minia, 61519 Egypt
Chemistry Department, Florida Institute of Technology, 150 W University Blvd, Melbourne, Florida, 32901 USA
E-mail: [email protected]; [email protected]Search for more papers by this authorAlan B. Brown
Chemistry Department, Florida Institute of Technology, 150 W University Blvd, Melbourne, Florida, 32901 USA
Search for more papers by this authorEssmat M. El-Sheref,
Alan B. Brown,
Corresponding Author
Essmat M. El-Sheref
Chemistry Department, Faculty of Science, Minia University, El Minia, 61519 Egypt
Chemistry Department, Florida Institute of Technology, 150 W University Blvd, Melbourne, Florida, 32901 USA
E-mail: [email protected]; [email protected]Search for more papers by this authorAlan B. Brown
Chemistry Department, Florida Institute of Technology, 150 W University Blvd, Melbourne, Florida, 32901 USA
Search for more papers by this authorAbstract
Although, recent reviews demonstrated intensively on the reactivity of dimethyl acetylenedicarboxylate (DMAD) in organic synthesis, its reactions have still get importance addition in that field. Moreover, and due to the huge amount of published literatures dealing with the reactions of DMAD, we are trying to give more focus on the important missed reactions in addition to give more light to updated publications. DMAD is an organic compound with the formula (C6H6O4), and it is a diester in which the ester groups are conjugated with a triple bond. As such, DMAD is highly electrophilic and a widely employed as a dienophile in cycloaddition reactions, like the Diels–Alder reaction. Many organic compounds specially the heterocyclic ones were prepared via its reactions.
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