How to cite this article: Kocijan A, Conradi M, Schön PM. 2012. Austenitic and duplex stainless steels in simulated physiological solution characterized by electrochemical and X-ray photoelectron spectroscopy studies. J Biomed Mater Res Part B 2012:100B:799–807.

Read the full text

About

PDF

Tools

Share a link

Email
Wechat
Bluesky

Abstract

A study of oxide layers grown on 2205 duplex stainless steel (DSS) and AISI 316L austenitic stainless steel in simulated physiological solution is presented here in order to establish the possibility of replacement of AISI 316 L with 2205 DSS in biomedical applications. The results of the potentiodynamic measurements show that the extent of the passive range significantly increased for DSS 2205 compared to AISI 316L stainless steel. Cyclic voltammetry was used to investigate electrochemical processes taking place on the steel surfaces. Oxide layers formed by electrochemical oxidation at different oxidation potentials were studied by X-ray photoelectron spectroscopy, and their compositions were analyzed as a function of depth. The main constituents on both the investigated materials were Cr- and Fe-oxides. Atomic force microscopy topography studies revealed the higher corrosion resistance of the DSS 2205 compared to the AISI 316L under the chosen experimental conditions. © 2012 Wiley Periodicals, Inc. J Biomed Mater Res Part B: Appl Biomater, 2012.

REFERENCES

1 Potgieter JH, Olubambi PA, Cornish L, Machio CN, Sherif ESM. Influence of nickel additions on the corrosion behaviour of low nitrogen 22% Cr series duplex stainless steels. Corros Sci 2008; 50: 2572–2579.
10.1016/j.corsci.2008.05.023
CAS Web of Science® Google Scholar
2 Ibrahim MAM, El Rehim SSA, Hamza MM. Corrosion behavior of some austenitic stainless steels in chloride environments. Mater Chem Phys 2009; 115: 80–85.
10.1016/j.matchemphys.2008.11.016
CAS Web of Science® Google Scholar
3 Hryniewicz T, Rokicki R, Rokosz K. Corrosion characteristics of medical-grade AISI Type 316L stainless steel surface after electropolishing in a magnetic field. Corrosion 2008; 64: 660–665.
10.5006/1.3279927
CAS Web of Science® Google Scholar
4 Finsgar M, Fassbender S, Hirth S, Milosev I. Electrochemical and XPS study of polyethyleneimines of different molecular sizes as corrosion inhibitors for AISI 430 stainless steel in near-neutral chloride media. Mater Chem Phys 2009; 116: 198–206.
10.1016/j.matchemphys.2009.03.010
CAS Web of Science® Google Scholar
5 Vignal V, Delrue O, Heintz O, Peultier J. Influence of the passive film properties and residual stresses on the micro-electrochemical behavior of duplex stainless steels. Electrochimica Acta 2010; 55: 7118–7125.
10.1016/j.electacta.2010.06.050
CAS Web of Science® Google Scholar
6 Platt JA, Guzman A, Zuccari A, Thornburg DW, Rhodes BF, Oshida Y, Moore BK. Corrosion behavior of 2205 duplex stainless steel. Am J Orthodont Dentofac Orthoped 1997; 112: 69–79.
10.1016/S0889-5406(97)70276-2
CAS PubMed Web of Science® Google Scholar
7 Raison-Peyron N. Implants and prostheses (excluding dentistry) and metal allergies. Revue Francaise D Allergol 2010; 50: S23–S28.
10.1016/S1877-0320(10)70010-5
Web of Science® Google Scholar
8 Shirley DA. High-resolution X-ray photoemission spectrum of valence bands of gold. Phys Rev B 1972; 5: 4709.
10.1103/PhysRevB.5.4709
Web of Science® Google Scholar
9 Fairley N. CasaXPS VAMAS Processing Software. http://www. casaxps.com/.
Google Scholar
10 Veleva L, Alpuche-Aviles MA, Graves-Brook MK, Wipf DO. Voltammetry and surface analysis of AISI 316 stainless steel in chloride-containing simulated concrete pore environment. J Electroanal Chem 2005; 578: 45–53.
10.1016/j.jelechem.2004.12.019
CAS Web of Science® Google Scholar
11 Kocijan A, Donik C, Jenko M. The electrochemical study of duplex stainless steel in chloride solutions. Mater Tehnol 2009; 43: 39–42.
CAS Web of Science® Google Scholar
12 Kocijan A, Merl DK, Jenko M. The corrosion behaviour of austenitic and duplex stainless steels in artificial saliva with the addition of fluoride. Corros Sci 2011; 53: 776–783.
10.1016/j.corsci.2010.11.010
CAS Web of Science® Google Scholar
13 Souto RM, Rosca ICM, Gonzalez S. Resistance to localized corrosion of passive films on a duplex stainless steel. Corrosion 2001; 57: 300–306.
10.5006/1.3290353
CAS Web of Science® Google Scholar
14 Ramasubramanian N, Preocanin N, Davidson RD. Analysis of passive films on stainless-steel by cyclic voltammetry and auger-spectroscopy. J Electrochem Soc 1985; 132: 793–798.
10.1149/1.2113959
CAS Web of Science® Google Scholar
15 Hocking WH, Stanchell FW, McAlpine E, Lister DH. Mechanisms of corrosion of stellite-6 in lithiated high-temperature water. Corros Sci 1985; 25: 531–557.
10.1016/0010-938X(85)90031-9
CAS Web of Science® Google Scholar
16 Abreu CM, Cristobal MJ, Losada R, Novoa XR, Pena G, Perez MC. High frequency impedance spectroscopy study of passive films formed on AISI 316 stainless steel in alkaline medium. J Electroanal Chem 2004; 572: 335–345.
10.1016/j.jelechem.2004.01.015
CAS Web of Science® Google Scholar
17 Clayton CR, Lu YC. A Bipolar model of the passivity of stainless-steel—The role of mo addition. J Electrochem Soc 1986; 133: 2465–2473.
10.1149/1.2108451
CAS Web of Science® Google Scholar
18 Donik C, Mandrino D, Jenko M. Depth profiling and angular dependent XPS analysis of ultra thin oxide film on duplex stainless steel. Vacuum 2010; 84: 1266–1269.
10.1016/j.vacuum.2010.01.057
CAS Web of Science® Google Scholar
19 Mandrino D, Donik C, Jenko M. AES of thin oxide layers on a duplex stainless steel surface. Surf Interf Anal 2010; 42: 762–765.
10.1002/sia.3212
CAS Web of Science® Google Scholar
20 Dabala M, Calliari I, Variola A. Corrosion behavior of a superduplex stainless steel in chloride aqueous solution. J Mater Eng Perform 2004; 13: 237–240.
10.1361/10599490418316
CAS Web of Science® Google Scholar
21 Kocijan A, Donik C, Jenko M. Electrochemical and XPS studies of the passive film formed on stainless steels in borate buffer and chloride solutions. Corros Sci 2007; 49: 2083–2098.
10.1016/j.corsci.2006.11.001
CAS Web of Science® Google Scholar
22 Elfstrom BO. Effect of chloride-ions on passive layers on stainless-steels. Mater Sci Eng 1980; 42: 173–180.
10.1016/0025-5416(80)90026-9
Web of Science® Google Scholar

Citing Literature

Volume100B, Issue3

April 2012

Pages 799-807

Austenitic and duplex stainless steels in simulated physiological solution characterized by electrochemical and X-ray photoelectron spectroscopy studies^†

Abstract

REFERENCES

Citing Literature

References

Information

About Wiley Online Library

Help & Support

Opportunities

Connect with Wiley

Austenitic and duplex stainless steels in simulated physiological solution characterized by electrochemical and X-ray photoelectron spectroscopy studies†

Abstract

REFERENCES

Citing Literature

References

Related

Information

Austenitic and duplex stainless steels in simulated physiological solution characterized by electrochemical and X-ray photoelectron spectroscopy studies^†