Studies on organophosphorus compounds 81. A novel synthetic approach to substituted cyclopentane-1,1-diylbisphosphonates via Pd(0) catalyzed enyne cyclization^†

Chaozhong Li,

Chaozhong Li

Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

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Chengye Yuan,

Corresponding Author

Chengye Yuan

Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, ChinaSearch for more papers by this author

Chaozhong Li,

Chaozhong Li

Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

Search for more papers by this author

Chengye Yuan,

Corresponding Author

Chengye Yuan

Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, ChinaSearch for more papers by this author

First published: October 1993

https://doi.org/10.1002/hc.520040518

Citations: 10

^†

Dedicated to Prof. Antonino Fava on the occasion of his seventieth birthday.

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Abstract

Intramolecular enyne cycloisomerization reactions catalyzed by Pd(PPh₃)₄ gave 4-substituted 3-methylenecyclopentane-1,1-diylbisphosphonates in good yield.

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Studies on organophosphorus compounds 81. A novel synthetic approach to substituted cyclopentane-1,1-diylbisphosphonates via Pd(0) catalyzed enyne cyclization^†

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Studies on organophosphorus compounds 81. A novel synthetic approach to substituted cyclopentane-1,1-diylbisphosphonates via Pd(0) catalyzed enyne cyclization†

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Studies on organophosphorus compounds 81. A novel synthetic approach to substituted cyclopentane-1,1-diylbisphosphonates via Pd(0) catalyzed enyne cyclization^†