Oxidation of allyl-substituted allene episulfides with a peracid gave the corresponding allene episulfide S-oxides which were found to undergo ready isomerization to bicyclo[2.1.1]thiahexane S-oxide derivatives on thermolysis or under acid-catalyzed reaction conditions.

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Formation of allyl-substituted allene episulfide S-oxides and their thermal and acid-catalyzed rearrangements^†

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Formation of allyl-substituted allene episulfide S-oxides and their thermal and acid-catalyzed rearrangements†

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Formation of allyl-substituted allene episulfide S-oxides and their thermal and acid-catalyzed rearrangements^†