Volume 4, Issue 5 pp. 421-426

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Reactions of triarylphosphines with organolithium reagents. Formation of biaryls^†

Yuzuru Uchida,

Corresponding Author

Yuzuru Uchida

Department of Applied Chemistry, Osaka Institute of Technology, Asahi-ku, Osaka 535, Japan

Yuzuru Uchida, Department of Applied Chemistry, Osaka Institute of Technology, Asahi-ku, Osaka 535, Japan

Shigeru Oae, Institute of Heteroatom Chemistry, Mihara-cho, Minamikawachi-gun, Osaka 587, Japan

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Masaaki Kawai,

Masaaki Kawai

Department of Applied Chemistry, Osaka Institute of Technology, Asahi-ku, Osaka 535, Japan

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Haruo Masauji,

Haruo Masauji

Department of Applied Chemistry, Osaka Institute of Technology, Asahi-ku, Osaka 535, Japan

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Shigeru Oae,

Corresponding Author

Shigeru Oae

Institute of Heteroatom Chemistry, Mihara-cho, Minamikawachi-gun, Osaka 587, Japan

Yuzuru Uchida, Department of Applied Chemistry, Osaka Institute of Technology, Asahi-ku, Osaka 535, Japan

Shigeru Oae, Institute of Heteroatom Chemistry, Mihara-cho, Minamikawachi-gun, Osaka 587, Japan

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Yuzuru Uchida,

Corresponding Author

Yuzuru Uchida

Department of Applied Chemistry, Osaka Institute of Technology, Asahi-ku, Osaka 535, Japan

Yuzuru Uchida, Department of Applied Chemistry, Osaka Institute of Technology, Asahi-ku, Osaka 535, Japan

Shigeru Oae, Institute of Heteroatom Chemistry, Mihara-cho, Minamikawachi-gun, Osaka 587, Japan

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Masaaki Kawai,

Masaaki Kawai

Department of Applied Chemistry, Osaka Institute of Technology, Asahi-ku, Osaka 535, Japan

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Haruo Masauji,

Haruo Masauji

Department of Applied Chemistry, Osaka Institute of Technology, Asahi-ku, Osaka 535, Japan

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Shigeru Oae,

Corresponding Author

Shigeru Oae

Institute of Heteroatom Chemistry, Mihara-cho, Minamikawachi-gun, Osaka 587, Japan

Yuzuru Uchida, Department of Applied Chemistry, Osaka Institute of Technology, Asahi-ku, Osaka 535, Japan

Shigeru Oae, Institute of Heteroatom Chemistry, Mihara-cho, Minamikawachi-gun, Osaka 587, Japan

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First published: October 1993

https://doi.org/10.1002/hc.520040503

Citations: 12

^†

This article is dedicated to Prof. Antonino Fava on the occasion of his seventieth birthday.

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Abstract

Triarylphosphines bearing 2-pyridyl or 2-benzothiazyl groups react with organolithium reagents at −78°C in THF to afford both coupling products and ligand exchanged triarylphosphines. The ligand coupling and ligand exchange are considered to take place via an intermediate formed by the nucleophilic attack of a lithium reagent on the phosphorus atom.

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Reactions of triarylphosphines with organolithium reagents. Formation of biaryls^†