Azidophosphanes are versatile reactants in the Staudinger reaction. The azides Cl₂PN₃ (1), (Et₂N)ClPN₃ (2), and (Et₂N)₂PN₃ (3) react with phosphanes to give the N-phosphanyl phosphazenes 4–10. (Et₂N)P(N₃)₂ is oxidized by PhN₃ yielding (Et₂N)P(N₃)₂NPh (11), which with PPh₃ yields the di- and triphosphazenes 12 and 13.

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