First Examples of the Atherton–Todd-Like Reaction in the Absence of Bases
Corresponding Author
Boris A. Trofimov
E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russian Federation
Correspondence to: Boris A. Trofimov; e-mail: [email protected].Search for more papers by this authorNina K. Gusarova
E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russian Federation
Search for more papers by this authorPavel А. Volkov
E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russian Federation
Search for more papers by this authorNina I. Ivanova
E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russian Federation
Search for more papers by this authorKseniya O. Khrapova
E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russian Federation
Search for more papers by this authorCorresponding Author
Boris A. Trofimov
E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russian Federation
Correspondence to: Boris A. Trofimov; e-mail: [email protected].Search for more papers by this authorNina K. Gusarova
E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russian Federation
Search for more papers by this authorPavel А. Volkov
E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russian Federation
Search for more papers by this authorNina I. Ivanova
E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russian Federation
Search for more papers by this authorKseniya O. Khrapova
E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russian Federation
Search for more papers by this authorABSTRACT
Oxidative cross-coupling between secondary phosphine chalcogenides and alcohols or phenols proceeds in CCl4 medium at 80–82°C to afford phosphinoсhalcogenоic O-esters in up to 92% yield. These couplings represent first examples of the Atherton–Todd-like reaction occurring in the absence of bases.
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