Volume 27, Issue 1 pp. 32-36
Short Communication
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Synthesis and Characterization of a Novel Two-Dimensional Network Polymer Containing 18- and 26-Membered Organotin Macrocycles

Qingfeng Wang

Corresponding Author

Qingfeng Wang

Department of Chemistry, Taishan University, Taian 271021, People's Republic of China

Correspondence to: Qingfeng Wang; e-mail: [email protected].Search for more papers by this author
Jianping Zhang

Jianping Zhang

Department of Chemistry, Taishan University, Taian 271021, People's Republic of China

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Yinfeng Han

Yinfeng Han

Department of Chemistry, Taishan University, Taian 271021, People's Republic of China

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First published: 27 August 2015
Citations: 3

ABSTRACT

The reaction of 4-mercaptophenylacetic acid with dimethyltin dichloride in the presence of sodium ethoxide in ethanol affords a novel two-dimensional organotin network structure compound 1, which is an unusual network containing dinuclear 18-membered and tetranuclear 26-membered organotin macrocycles. The compound has been characterized by elemental analysis, IR, and 1H, 13C, and 119Sn NMR spectroscopy. Furthermore, we have also characterized the compound by X-ray crystallography.

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