Short Communication
Free to Read
О,О-Dialkyl-S-(1,1-dimethyl-2-oxoethyl)dithiophosphates: Synthesis and Reactions with n-Nucleophiles
Contract grant sponsor: Russian Foundation for Basic Research.
Contract grant number: 13.03-97098/2013.
Contract grant sponsor: Ministry of Education and Science of Russian Federation (within the basic part of task #2014/56).
ABSTRACT
Hydrolysis of the new types of iminium salts was used to synthesize О,О-dialkyl-S-(1,1-dimethyl-2-oxoethyl)dithiophosphates or 2-dialkoxythiophosphorylthio-substituted aldehydes with carbon isochain. Reactions of aldehydes with N-, N,N-, and O,N-nucleophiles gave new phosphorylated imines containing an acetal group at different positions, perhydro-1,3-diazol and oxazol with the diisopropoxythiophosphorylthio group in a side chain, and hydrazone of this aldehyde and diphenylphosphinylacetic acid hydrazide.
