A Novel Tetranuclear Organotin(IV) Carboxylate with Chain Structure: Synthesis, Crystal Structure, and Characterizations
Aboubacar Sidiki Sougoule
Department of Chemistry, Northeast Normal University, Changchun, 130024 People's Republic of China
Department of Chemistry, University Gamal Abdel Nasser of Conakry, 1147 Republic of Guinea
Search for more papers by this authorCheick Abdoul balde
Department of Chemistry, University Gamal Abdel Nasser of Conakry, 1147 Republic of Guinea
Search for more papers by this authorNamory Keita
Department of Biology, Northeast Normal University, Changchun, 130024 People's Republic of China
Search for more papers by this authorXiao Xiao
Department of Chemistry, Northeast Normal University, Changchun, 130024 People's Republic of China
Search for more papers by this authorXiao Han
Department of Chemistry, Northeast Normal University, Changchun, 130024 People's Republic of China
Search for more papers by this authorJingwen Liang
Department of Chemistry, Northeast Normal University, Changchun, 130024 People's Republic of China
Search for more papers by this authorCorresponding Author
Dongsheng Zhu
Department of Chemistry, Northeast Normal University, Changchun, 130024 People's Republic of China
Correspondence to: Dongsheng Zhu; e-mail: [email protected].Search for more papers by this authorAboubacar Sidiki Sougoule
Department of Chemistry, Northeast Normal University, Changchun, 130024 People's Republic of China
Department of Chemistry, University Gamal Abdel Nasser of Conakry, 1147 Republic of Guinea
Search for more papers by this authorCheick Abdoul balde
Department of Chemistry, University Gamal Abdel Nasser of Conakry, 1147 Republic of Guinea
Search for more papers by this authorNamory Keita
Department of Biology, Northeast Normal University, Changchun, 130024 People's Republic of China
Search for more papers by this authorXiao Xiao
Department of Chemistry, Northeast Normal University, Changchun, 130024 People's Republic of China
Search for more papers by this authorXiao Han
Department of Chemistry, Northeast Normal University, Changchun, 130024 People's Republic of China
Search for more papers by this authorJingwen Liang
Department of Chemistry, Northeast Normal University, Changchun, 130024 People's Republic of China
Search for more papers by this authorCorresponding Author
Dongsheng Zhu
Department of Chemistry, Northeast Normal University, Changchun, 130024 People's Republic of China
Correspondence to: Dongsheng Zhu; e-mail: [email protected].Search for more papers by this authorContract grant sponsor: Science and Technology Department of Jilin Province. Contract grant numbers: 20120440 and 20130206109SF.
ABSTRACT
A new tetranuclear organotin carboxylate {[(n-Bu2SnO)2L]2}n (complex 1) was synthesized by the reaction of di-n-butyltin oxide with (p-carboxymethoxy-phenoxy) acetic acid (LH2) and characterized by elemental analyses: IR, UV–visible, 1H, 13C, 119Sn NMR spectroscopy and single crystal X-ray study. X-ray crystallography diffraction data revealed that the complex 1 was polymeric fashion with a chain structure containing a ladder-like tetranuclear organo-oxotin cluster. In the complex 1, the ligand LH2 is coordinated to the central tin(IV) atoms via the carboxylato-O atoms. The tetranuclear tin system is formed by the bridges through the carbonyl oxygen atom of the carboxylate moieties and making the tin atom of pentacoordinated in distorted trigonal bipyramidal geometry. Single crystal X-ray data indicate that the complex 1 crystallized in the cubic system with the space group C2/c.
Supporting Information
Disclaimer: Supplementary materials have been peer-reviewed but not copyedited.
| Filename | Description |
|---|---|
| hc21271-sup-0001-NMR.docx648.3 KB | Supporting information |
| hc21271-sup-0002-tex.docx16.1 KB | Crystallographic data for the structural analysis have been deposited with the Cambridge Crystallographic Data Centre, CCDC No. 998540 for complex 1. Copies of this information may be obtained free of charge from: The Director, CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax: +44(1223)336-033; e-mail: [email protected] or www: http://www: ccdc.cam.ac.uk). |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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