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Ni-Catalyzed Cross-Coupling Reaction: The Direct Synthesis of Symmetrical Disulfanes from Aryl and Primary Alkyl Halides
Mohammad Soleiman-Beigi,
Zeinab Arzehgar,
Corresponding Author
Mohammad Soleiman-Beigi
Department of Chemistry, Basic of Sciences Faculty, Ilam University, Ilam, Iran
Correspondence to: Mohammad Soleiman-Beigi; e-mail: [email protected]; [email protected].Search for more papers by this authorZeinab Arzehgar
Department of Chemistry, Basic of Sciences Faculty, Ilam University, Ilam, Iran
Search for more papers by this authorMohammad Soleiman-Beigi,
Zeinab Arzehgar,
Corresponding Author
Mohammad Soleiman-Beigi
Department of Chemistry, Basic of Sciences Faculty, Ilam University, Ilam, Iran
Correspondence to: Mohammad Soleiman-Beigi; e-mail: [email protected]; [email protected].Search for more papers by this authorZeinab Arzehgar
Department of Chemistry, Basic of Sciences Faculty, Ilam University, Ilam, Iran
Search for more papers by this authorABSTRACT
A novel Ni-catalyzed cross-coupling reaction is introduced for the direct synthesis of diaryldisulfanes and dialkyldisulfanes from aryl halides and primary alkyl halides at normal atmospheric conditions, respectively. This one-pot and domino protocol utilizes only 10 mol% of NiCl2 as a catalyst and morpholin-4-ium morpholine-4-carbo-dithioate as a new, stable, solid, and odorless sulfurating reagent in the presence of ethylene glycol as a cosolvent and bidentate ligand in dimethyl formamide (DMF) at 130°C with good to excellent yields and relatively short time reaction.
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