Center of Research Excellence in Petroleum Refining and Petrochemicals, Research Institute, King Fahd University of Petroleum & Minerals, Dhahran, 31261 Kingdom of Saudi Arabia

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Zafar Ali Khan Khattak,

Zafar Ali Khan Khattak

Department of Chemistry, Quaid-i-Azam University, Islamabad, 45320 Pakistan

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Zia-ur -Rehman,

Corresponding Author

Zia-ur -Rehman

Department of Chemistry, Quaid-i-Azam University, Islamabad, 45320 Pakistan

Correspondence to: Zia-ur-Rehman; e-mail: [email protected], [email protected].Search for more papers by this author

Azam Khan,

Azam Khan

Department of Chemistry, Quaid-i-Azam University, Islamabad, 45320 Pakistan

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Afzal Shah,

Afzal Shah

Department of Chemistry, Quaid-i-Azam University, Islamabad, 45320 Pakistan

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Waqar Zaid,

Waqar Zaid

Department of Chemistry, Quaid-i-Azam University, Islamabad, 45320 Pakistan

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Amin Badshah,

Amin Badshah

Department of Chemistry, Quaid-i-Azam University, Islamabad, 45320 Pakistan

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Mohammed Fettouhi,

Mohammed Fettouhi

Department of Chemistry, King Fahd University of Petroleum and Minerals, Dhahran, Kingdom of Saudi Arabia

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Atif Fazal,

Atif Fazal

Center of Research Excellence in Petroleum Refining and Petrochemicals, Research Institute, King Fahd University of Petroleum & Minerals, Dhahran, 31261 Kingdom of Saudi Arabia

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First published: 23 May 2014

https://doi.org/10.1002/hc.21167

Citations: 2

Contract grant sponsor: Higher Education Commission of Pakistan.

Contract grant sponsor: Quaid-i-Azam University.

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ABSTRACT

This article presents a new heteroleptic Zn(II) dithiocarbamate (1) having molecules linked together via H···H and π···π interactions to form a giant hexanuclear macrocycle. These macrocycles are connected together through S···H interactions to offer a unique two-dimensional cloth-like interwoven architecture in the solid state. The redox behavior of the complex deposited on the surface of a glassy carbon electrode was investigated in different pH media. The analyte was found to oxidize and reduce in a pH-dependent irreversible manner. On the basis of the electrochemical findings, redox mechanistic pathways were proposed.

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Self-Assembled Heteroleptic Zn(II) Dithiocarbamate-Based 2D-Interwoven Supramolecular Giant Macrocycles and Their Redox Properties

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Self-Assembled Heteroleptic Zn(II) Dithiocarbamate-Based 2D-Interwoven Supramolecular Giant Macrocycles and Their Redox Properties

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