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On the Intramolecular Interactions of Si/P in 1,2-Phenylene Frameworks

Corresponding Author

Takanobu Sanji

Chemical Resources Laboratory, Tokyo Institute of Technology, Yokohama 226-8503 Japan

Correspondence to: Takanobu Sanji; e-mail: [email protected]. Masato Tanaka; e-mail: [email protected].Search for more papers by this author

Keigo Naito,

Keigo Naito

Chemical Resources Laboratory, Tokyo Institute of Technology, Yokohama 226-8503 Japan

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Taigo Kashiwabara,

Taigo Kashiwabara

Chemical Resources Laboratory, Tokyo Institute of Technology, Yokohama 226-8503 Japan

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Masato Tanaka,

Corresponding Author

Masato Tanaka

Chemical Resources Laboratory, Tokyo Institute of Technology, Yokohama 226-8503 Japan

Correspondence to: Takanobu Sanji; e-mail: [email protected]. Masato Tanaka; e-mail: [email protected].Search for more papers by this author

Takanobu Sanji,

Corresponding Author

Takanobu Sanji

Chemical Resources Laboratory, Tokyo Institute of Technology, Yokohama 226-8503 Japan

Correspondence to: Takanobu Sanji; e-mail: [email protected]. Masato Tanaka; e-mail: [email protected].Search for more papers by this author

Keigo Naito,

Keigo Naito

Chemical Resources Laboratory, Tokyo Institute of Technology, Yokohama 226-8503 Japan

Search for more papers by this author

Taigo Kashiwabara,

Taigo Kashiwabara

Chemical Resources Laboratory, Tokyo Institute of Technology, Yokohama 226-8503 Japan

Search for more papers by this author

Masato Tanaka,

Corresponding Author

Masato Tanaka

Chemical Resources Laboratory, Tokyo Institute of Technology, Yokohama 226-8503 Japan

Correspondence to: Takanobu Sanji; e-mail: [email protected]. Masato Tanaka; e-mail: [email protected].Search for more papers by this author

First published: 15 August 2012

https://doi.org/10.1002/hc.21044

Citations: 5

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Abstract

The synthesis and structure of 1-diphenylphosphino-2-(fluorodiphenylsilyl) benzene 1 and 1-diphenylphosphino-2-(difluorophenylsilyl)- benzene 2 are reported. An X-ray crystal structure analysis of 1 shows a weak interaction between the silicon and phosphorus moieties, producing a hypervalent state at the silicon. The hypervalent state of the silicon is also supported by a natural bond orbital calculation. However, despite having a difluorosilyl group, 2 does not show a hypervalent state for the silicon, based on an X-ray crystal structure analysis. © 2012 Wiley Periodicals, Inc. Heteroatom Chem 00:1–5, 2012; View this article online at wileyonlinelibrary.com. DOI 10.1002/hc.21044

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Filename	Description
hc21044-sup-0001-TableS1.txt403.4 KB	CCDC-876980 (1) and CCDC-876981 (2) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; fax: +44 1223 336033; or [email protected]).
hc21044-sup-0002-TableS2.txt349.5 KB	NMR for new compounds and NBO analysis are available in the Supporting Information.
hc21044-sup-0003-S1.pdf1.3 MB	Supporting Information

On the Intramolecular Interactions of Si/P in 1,2-Phenylene Frameworks

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On the Intramolecular Interactions of Si/P in 1,2-Phenylene Frameworks

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