The reaction of 2-bromopyridine with a PH3/H2 system in the KOH/DMSO suspension: A short route to tris(2-pyridyl)phosphine
Corresponding Author
Boris A. Trofimov
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russian Federation
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russian FederationSearch for more papers by this authorNina K. Gusarova
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russian Federation
Search for more papers by this authorAlexander V. Artem'ev
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russian Federation
Search for more papers by this authorSvetlana F. Malysheva
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russian Federation
Search for more papers by this authorNataliya A. Belogorlova
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russian Federation
Search for more papers by this authorAnastasiya O. Korocheva
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russian Federation
Search for more papers by this authorCorresponding Author
Boris A. Trofimov
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russian Federation
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russian FederationSearch for more papers by this authorNina K. Gusarova
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russian Federation
Search for more papers by this authorAlexander V. Artem'ev
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russian Federation
Search for more papers by this authorSvetlana F. Malysheva
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russian Federation
Search for more papers by this authorNataliya A. Belogorlova
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russian Federation
Search for more papers by this authorAnastasiya O. Korocheva
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky Str., 664033 Irkutsk, Russian Federation
Search for more papers by this authorAbstract
The straightforward reaction of 2-bromopyridine with a PH3/H2 system (generated from phosphorus red and aqueous alkali) in the superbasic KOH/DMSO/(H2O) suspension under mild conditions (70°C, 1.5 h, atmospheric pressure) affords selectively and cleanly tris(2-pyridyl)phosphine in 50% yield; no admixtures of the expected primary and secondary pyridylphosphines were observed in the crude product. © 2012 Wiley Periodicals, Inc. Heteroatom Chem 23:411–414, 2012; View this article online at wileyonlinelibrary.com. DOI 10.1002/hc.21030
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