A novel stereoselective synthesis of (Z)-α-arylsulfanyl-α,β-unsaturated ketones via Stille coupling of (E)-α-arylsulfanylvinylstannanes with acyl halides
Fang Yao
School of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, People's Republic of China
Department of Chemistry and Pharmaceutical Engineering, West Branch of Zhejiang University of Technology, Quzhou 324000, People's Republic of China
Search for more papers by this authorShengyong You
School of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, People's Republic of China
Search for more papers by this authorCorresponding Author
Mingzhong Cai
School of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, People's Republic of China
School of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, People's Republic of ChinaSearch for more papers by this authorFang Yao
School of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, People's Republic of China
Department of Chemistry and Pharmaceutical Engineering, West Branch of Zhejiang University of Technology, Quzhou 324000, People's Republic of China
Search for more papers by this authorShengyong You
School of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, People's Republic of China
Search for more papers by this authorCorresponding Author
Mingzhong Cai
School of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, People's Republic of China
School of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, People's Republic of ChinaSearch for more papers by this authorAbstract
(E)-α-Arylsulfanylvinylstannanes react with acyl halides in the presence of a catalytic amount of Pd(PPh3)4 and CuI cocatalyst to give stereoselectively the corresponding (Z)-α-arylsulfanyl-α,β-unsaturated ketones in good yields. © 2009 Wiley Periodicals, Inc. Heteroatom Chem 20:218–223, 2009; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20536
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