Disilyl dithiophosphonates in the synthesis of open chain and cyclic organothiophosphorus compounds
Corresponding Author
Il'yas S. Nizamov
Kazan State Pedagogical University, Mezhlauk Str. 1, 420021 Kazan, Russia
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, RussiaSearch for more papers by this authorGul'nur G. Sergeenko
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia
Search for more papers by this authorIl'nar D. Nizamov
Kazan State Pedagogical University, Mezhlauk Str. 1, 420021 Kazan, Russia
Search for more papers by this authorYan E. Popovich
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia
Search for more papers by this authorRavil N. Khaibullin
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia
Search for more papers by this authorLyubov A. Al'metkina
Orenburg State University, Prospekt Pobedy, 13, 460352 Orenburg, Russia
Search for more papers by this authorBoris E. Abalonin
Kazan State Pedagogical University, Mezhlauk Str. 1, 420021 Kazan, Russia
Search for more papers by this authorElvira S. Batyeva
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia
Search for more papers by this authorDmitry B. Krivolapov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia
Search for more papers by this authorIgor A. Litvinov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia
Search for more papers by this authorCorresponding Author
Il'yas S. Nizamov
Kazan State Pedagogical University, Mezhlauk Str. 1, 420021 Kazan, Russia
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, RussiaSearch for more papers by this authorGul'nur G. Sergeenko
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia
Search for more papers by this authorIl'nar D. Nizamov
Kazan State Pedagogical University, Mezhlauk Str. 1, 420021 Kazan, Russia
Search for more papers by this authorYan E. Popovich
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia
Search for more papers by this authorRavil N. Khaibullin
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia
Search for more papers by this authorLyubov A. Al'metkina
Orenburg State University, Prospekt Pobedy, 13, 460352 Orenburg, Russia
Search for more papers by this authorBoris E. Abalonin
Kazan State Pedagogical University, Mezhlauk Str. 1, 420021 Kazan, Russia
Search for more papers by this authorElvira S. Batyeva
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia
Search for more papers by this authorDmitry B. Krivolapov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia
Search for more papers by this authorIgor A. Litvinov
A. E. Arbuzov Institute of Organic and Physical Chemistry, Russian Academy of Sciences, Arbuzov Str. 8, 420088 Kazan, Russia
Search for more papers by this authorAbstract
O-(Trimethylsiloxy)alkyl S-trimethylsilyl aryldithiophosphonates 7a–d were obtained by the reaction of 2,4-diaryl-1,3,2,4-dithiadiphosphetane-2,4-disulfides 5a,b with disilyl derivatives of glycols 6a,c and salicyl alcohol 6b. The reactions of mixed O,S-bis(trimethylsilyl) 2,4-di(3,5-di-tert-butyl-4-hydroxyphenyl)dithiophosphonate 1 and S-silyl aryldithiophosphonates 7a,b with S,S-diethyldithiodiphenylgermane 2, dichlorodiphenylgermane 8a, and dichlorodiphenylstannane 8b were studied. The structure of hexaphenyl-2,4,6,1,3,5-trithiatrigerminane 11 was established by X-ray single crystal diffraction. © 2004 Wiley Periodicals, Inc. Heteroatom Chem 15:225–232, 2004; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.20009
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