Hollow NaTi1.9Sn0.1(PO4)3@C Nanoparticles for Anodes of Sodium-Ion Batteries with Superior Rate and Cycling Properties
Min Wang
School of Chemistry & Chemical Engineering, Beijing Institute of Technology, Beijing, 102488 China
Search for more papers by this authorCorresponding Author
Man Xie
Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science & Engineering, Beijing Institute of Technology, Beijing, 100081 China
Search for more papers by this authorZhiming Zhou
School of Chemistry & Chemical Engineering, Beijing Institute of Technology, Beijing, 102488 China
Search for more papers by this authorYongxin Huang
Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science & Engineering, Beijing Institute of Technology, Beijing, 100081 China
Search for more papers by this authorZiheng Wang
Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science & Engineering, Beijing Institute of Technology, Beijing, 100081 China
Search for more papers by this authorYang Mei
Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science & Engineering, Beijing Institute of Technology, Beijing, 100081 China
Search for more papers by this authorFeng Wu
Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science & Engineering, Beijing Institute of Technology, Beijing, 100081 China
Collaborative Innovation Center of Electric Vehicles in Beijing, Beijing, 100081 China
Search for more papers by this authorCorresponding Author
Renjie Chen
Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science & Engineering, Beijing Institute of Technology, Beijing, 100081 China
Collaborative Innovation Center of Electric Vehicles in Beijing, Beijing, 100081 China
Search for more papers by this authorMin Wang
School of Chemistry & Chemical Engineering, Beijing Institute of Technology, Beijing, 102488 China
Search for more papers by this authorCorresponding Author
Man Xie
Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science & Engineering, Beijing Institute of Technology, Beijing, 100081 China
Search for more papers by this authorZhiming Zhou
School of Chemistry & Chemical Engineering, Beijing Institute of Technology, Beijing, 102488 China
Search for more papers by this authorYongxin Huang
Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science & Engineering, Beijing Institute of Technology, Beijing, 100081 China
Search for more papers by this authorZiheng Wang
Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science & Engineering, Beijing Institute of Technology, Beijing, 100081 China
Search for more papers by this authorYang Mei
Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science & Engineering, Beijing Institute of Technology, Beijing, 100081 China
Search for more papers by this authorFeng Wu
Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science & Engineering, Beijing Institute of Technology, Beijing, 100081 China
Collaborative Innovation Center of Electric Vehicles in Beijing, Beijing, 100081 China
Search for more papers by this authorCorresponding Author
Renjie Chen
Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science & Engineering, Beijing Institute of Technology, Beijing, 100081 China
Collaborative Innovation Center of Electric Vehicles in Beijing, Beijing, 100081 China
Search for more papers by this authorAbstract
Herein, two strategies are simultaneously used to synthesize the hollow carbon-coated nanoparticles of NaTi1.9Sn0.1(PO4)3@C (NTSP@C). The porous morphology of NTST@C is controlled through a trace amount of tin doping while selecting a fire-new carbon source. The NTSP@C materials present a nanosized structure with a hollow morphology, exhibiting a large specific surface area of ≈71.0 m2 g−1 and a average bore diameter of ≈26.4 nm. Moreover, the carbon layer is ≈5 nm thick with a mass ratio of 6.81%. The NTSP@C sample displays an ultrastrong rate capability (128.8 mA h g−1 at 0.1 C and 101.5 mA h g−1 at 10 C at 1.5–3.0 V) and a superior cycling performance (126.3–115.8 mA h g−1 after 300 cycles at 1 C for a retention ratio of 91.7% and 101.4–87.1 mA h g−1 after 2000 cycles at 10 C for a retention ratio of 85.9%). These excellent electrochemical performances are due to the nanosized structure, unique morphology, and thin carbon layer as a conductive medium. It is clear that the NTSP@C material is a promising anode material that can be incorporated into sodium-ion batteries to achieve superior electrochemical performance.
Conflict of Interest
The authors declare no conflict of interest.
Supporting Information
| Filename | Description |
|---|---|
| ente201900079-sup-0001-SuppData-S1.docx1.1 MB | Supplementary |
Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
References
- 1Z. Yan, L. Liu, H. Shu, X. Yang, H. Wang, J. Tan, Q. Zhou, Z. Huang, X. Wang, J. Power Sources 2015, 274, 8.
- 2K. B. Hueso, M. Armand, T. Rojo, Energy Environ. Sci. 2013, 6, 734.
- 3X. Dong, L. Chen, X. Su, Y. Wang, Y. Xia, Angew. Chem., Int. Ed. 2016, 55, 7474.
- 4H. Gao, J. B. Goodenough, Angew. Chem., Int. Ed. 2016, 55, 12768.
- 5R. C. Massé, E. Uchaker, G. Cao, Sci. China Mater. 2015, 58, 715.
- 6A. Eftekhari, D. W. Kim, J. Power Sources 2018, 395, 336.
- 7M. Pasta, C. D. Wessells, R. A. Huggins, Y. Cui, Nat. Commun. 2012, 3, 1149.
- 8U. Nisar, R. Amin, R. Essehli, R. A. Shakoor, R. Kahraman, D. K. Kim, M. A. Khaleel, I. Belharouak, J. Power Sources 2018, 396, 774.
- 9Y. Wang, X. Yu, S. Xu, J. Bai, R. Xiao, Y.-S. Hu, H. Li, X.-Q. Yang, L. Chen, X. Huang, Nat. Commun. 2013, 4, 2365.
- 10G. Pang, P. Nie, C. Yuan, L. Shen, X. Zhang, H. Li, C. Zhang, J. Mater. Chem. A 2014, 2, 20659.
- 11J. Y. Hwang, S.-T. Myung, Y. K. Sun, Chem. Soc. Rev. 2017, 46, 3529.
- 12X. Li, X. Zhu, J. Liang, Z. Hou, Y. Wang, N. Lin, Y. Zhu, Y. Qian, J. Electrochem. Soc. 2014, 161, A1181.
- 13H. Kabbour, D. Coillot, M. Colmont, C. Masquelier, O. Mentre, J. Am. Chem. Soc. 2011, 133, 11900.
- 14Z. Li, D. Young, K. Xiang, W. C. Carter, Y. M. Chiang, Adv. Energy Mater. 2013, 3, 290.
- 15M. Sawicki, L. L. Shaw, RSC Adv. 2015, 5, 53129.
- 16U. Nisar, R. A. Shakoor, R. Essehli, R. Amin, B. Orayech, Z. Ahmad, P. R. Kumar, R. Kahraman, S. Al-Qaradawi, A. Soliman, Electrochim. Acta 2018, 292, 98.
- 17C. Delmas, F. Cherkaoui, A. Nadiri, P. Hagenmuller, Mat. Res. Bull. 1987, 22, 631.
- 18S. Chen, C. Wu, L. Shen, C. Zhu, Y. Huang, K. Xi, J. Maier, Y. Yu, Adv. Mater. 2017, 29, 1700431.
- 19Q. Hu, M. Yu, J. Liao, Z. Wen, C. Chen, J. Mater. Chem. A 2018, 6, 2365.
- 20T. Wei, G. Yang, C. Wang, ACS Appl. Mater. Interfaces 2017, 9, 31861.
- 21H. Liu, H. Zhou, L. Chen, Z. Tanga, W. Yang, J. Power Sources 2011, 196, 814.
- 22H. Liu, Y. Liu, Ceram. Int. 2018, 44, 5813.
- 23G. Pang, C. Yuan, P. Nie, B. Ding, J. Zhu, X. Zhang, Nanoscale 2014, 6, 6328.
- 24C. Wu, P. Kopold, Y.-L. Ding, A. Peter, J. Maier van Aken, Y. Yu, ACS Nano 2015, 9, 6610.
- 25L. Zhang, X. Wang, W. Deng, X. Zang, C. Liu, C. Li, J. Chen, M. Xue, R. Li, F. Pan, Nanoscale 2018, 10, 958.
- 26Y. Hua, X. Ma, P. Guo, F. Jaeger, Z. Wang, Ceram. Int. 2017, 43, 12338.
- 27I. N. Sivagami, K. Prasanna, P. Santhoshkumar, Y. N. Jo, G. Y. Seo, C. W. Lee, J. Alloys Compd. 2017, 697, 450.
- 28P. Hu, J. Ma, T. Wang, B. Qin, C. Zhang, C. Shang, J. Zhao, G. Cui, Chem. Mater. 2015, 27, 6668.
- 29B. Liu, Y. Xing, X. Sun, X. Liu, S. Hou, Mater. Lett. 2009, 63, 2548.
- 30M. Bian, L. Tian, Ceram. Int. 2017, 43, 9543.
- 31K. Cui, S. Hu, Y. Li, J. Power Sources 2016, 325, 465.
- 32L. Shen, Y. Wang, H. Lv, S. Chen, P. A. van Aken, X. Wu, J. Maier, Y. Yu, Adv. Mater. 2018, 30, 1804378.
- 33H. K. Roh, M. S. Kim, K. Chung, M. Ulaganathan, V. Aravindan, S. Madhavi, K. Roh, K. B. Kim, J. Mater. Chem. A 2017, 5, 17506.
- 34Y. Jiang, J. Shi, M. Wang, L. Zeng, L. Gu, Y. Yu, ACS Appl. Mater. Inter 2016, 8, 689.
- 35W. Duan, Z. Zhu, H. Li, Z. Hu, K. Zhang, F. Cheng, J. Chen, J. Mater. Chem. A 2014, 2, 8668.
- 36H. Kim, J. Hong, Y. U. Park, J. Kim, I. Hwang, K. Kang, Adv. Funct. Mater. 2015, 25, 534.
Citing Literature
