Synthesis, Structure and Magnetic Behavior of a Novel Series of Trinuclear Windwheel Complexes
Rong Luo
Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao, Shandong, 266100 China
Search for more papers by this authorChen-Ze Xie
Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao, Shandong, 266100 China
Search for more papers by this authorMing-Guang Chen
Baotou Research Institute of Rare Earths, Baotou, Inner Mongolia, 014040 China
Search for more papers by this authorHai-Yan Shi
State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian, 361005 China
Search for more papers by this authorXiang-Jian Kong
State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian, 361005 China
Search for more papers by this authorYu-Hua Fan
Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao, Shandong, 266100 China
Search for more papers by this authorCorresponding Author
Feng Shao
Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao, Shandong, 266100 China
E-mail: [email protected]Search for more papers by this authorRong Luo
Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao, Shandong, 266100 China
Search for more papers by this authorChen-Ze Xie
Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao, Shandong, 266100 China
Search for more papers by this authorMing-Guang Chen
Baotou Research Institute of Rare Earths, Baotou, Inner Mongolia, 014040 China
Search for more papers by this authorHai-Yan Shi
State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian, 361005 China
Search for more papers by this authorXiang-Jian Kong
State Key Laboratory of Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian, 361005 China
Search for more papers by this authorYu-Hua Fan
Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao, Shandong, 266100 China
Search for more papers by this authorCorresponding Author
Feng Shao
Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao, Shandong, 266100 China
E-mail: [email protected]Search for more papers by this authorComprehensive Summary
A new family of trinuclear windwheel complexes with molecular formula [MII3(tpa)3(μ-ttc)](ClO4)3·n(sol) (ttc = 1,3,5-triazine-2,4,6-trithiol; tpa = tris(2-pyridylmethyl)amine; M = Mn, n = 2, sol = CH3CN, 1; M = Co, n = 1, sol = CH3CN, 2; M = Ni, n = 0, 3) were synthesized and characterized. Single-crystal X-ray diffraction revealed that three metal centers in 1—3 are connected by ttc bridge, forming a regular triangular MII3 core. Each metal center is bonded by chelating S, N atoms from ttc and by N atoms from tpa. Magnetic studies showed that 1—3 displayed antiferromagnetic behavior and further gave the easy-axis anisotropy (D = −0.77 cm−1 for 1 and −8.13 cm−1 for 2) and easy-plane anisotropy (D = 5.08 cm−1 for 3). Moreover, 2 exhibited field-induced slow magnetic relaxation behavior and their effective energy barriers were roughly evaluated Ueff = 6.9 K.
Supporting Information
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